Química de La Contaminación Ambiental

UNIVERSIDAD DEL VALLE - FACULTAD DE INGENIERA

ESCUELA DE INGENIERA DE RECURSOS NATURALES Y DEL AMBIENTE

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INFORMACIN GENERAL 1.1 ASIGNATURA : QUMICA DE LA CONTAMINACIN AMBIENTAL 1.2 CODIGO : 730027 1.3 PRERREQUISITOS : Ninguno 1.6 SEMESTRE : Primero 1.7 INTENSIDAD HORARIA : 44 horas/semestre 1.8 HABILITABLE : No 1.9 VALIDABLE : No 1.10 PROFESOR : Luz Edith Barba Ho 1.11 PERIODO ACADEMICO : agosto-diciembre 2. OBJETIVOS a. GENERAL

Adquirir conocimientos fundamentales de la qumica del agua, aire y suelo y sobre el comportamiento qumico de las sustancias contaminantes en el ambiente.

b. ESPECFICOS

Comprender las interacciones lquido-slido-gas involucrados en los fenmenos qumicos y bioqumicos que ocurren en el agua.

Evaluar la contaminacin de cuerpos de agua por compuestos orgnicos e inorgnicos.

Determinar el efecto de residuos y contaminantes sobre la calidad del suelo.

Conocer los contaminantes orgnicos e inorgnicos que afectan la atmsfera.

Conocer las diferentes tcnicas analticas que permiten identificar y cuantificar cantidades de contaminantes en muestras ambientales.



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SECCION UNIDAD BIBLIOGRAFIA

1

2,3

4

5,6

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Qumica Ambiental. Introduccin. Movimiento de los contaminantes. Dinmica qumica. AGUA: Calidad , cantidad Fuentes y usos del agua. Propiedades. Calidad de agua Fundamentos de Qumica Acutica Qumica de procesos Contaminacin Contaminantes en el agua. Parmetros Orgnicos indicadores de contaminacin Compuestos txicos

INTRODUCCION

QUMICA ACUTICA

CONTAMINACIN DEL AGUA

5.1, 5.2, 5.14 5.16, 5.17, 5.20, 5.43 - 5.48 5.59 5.1, 5.14, 5.17 5.1, 5.2, 5.14 5.15, 5.20,5.43 5.45, 5.46 5.5, 5.6, 5.8 5.1, 5.2, 5.14 5.7, 5.9, 5.16 5.17, 5.19,5.26 5.36 5.9, 5.18

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QUMICA DE L SUE LO.

Naturaleza y composicin del suelo. Aire y agua en el suelo Componentes orgnicos e inorgnicos del suelo Reacciones cido bsicas y de intercambio inico Macronutrientes y micronutrientes Desechos y polutantes del suelo

GEOSFERA Y SUELO

5.7, 5.24 5.43 - 5.48 5.37 5.42 5.39 5.35, 5.40, 5.58

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Qumica del aire Importancia y composicin de la atmsfera Reacciones qumicas y fotoqumicas Iones y radicales en la atmsfera Gases inorgnicos polutantes: CO-SO2, NOX Lluvia cida

NATURALEZA Y COMPOSICIN

DE LA ATMSFERA

5.3, 5.4, 5.43 - 5.48 5.20 5.29, 5.33 5.3, 5.4 5.29, 5.33 5.43, 5.48



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SECCION UNIDAD BIBLIOGRAFIA

Cloro y flor y sus componentes gaseosos

Laboratorio 1 2 3

Anlisis de aguas: Parmetros de calidad de agua Contaminantes en aguas residuales Instrumental. Elementos txicos-toxicidad

ANLISIS QUMICOS

AMBIENTALES

5.9, 5.18 5.63, 5.64 5.15, 5.53,5.11

3. METODOLOGA

El estudiante recibir una orientacin sobre cada rea del conocimiento de parte de profesionales especializados en cada tpico, con las ayudas didcticas adecuadas. La parte prctica constar de tres sesiones donde se suministrar al estudiante informacin sobre metodologas, equipos y tcnicas de laboratorio especializadas en el anlisis de muestras ambientales.

4. EVALUACION

Se realizarn dos (2) exmenes de la parte terica, talleres e informes de laboratorio, los cuales tendrn la siguiente asignacin: Examen escrito 1 : 30 % Examen escrito 2 : 30 % Talleres : 15 %

Informes de Laboratorio : 25 % 5. BIBLIOGRAFIA

TEXTOS GUIA:QUIMICA AMBIENTAL POSGRADO PISA.LUZ EDITH BARBA HO QUIMICA DEL AGUA. LUZ EDITH BARBA HO QUIMICA ASOCIADA CON LA CONTAMINACION DEL AGUA. LUZ EDITH BARBA HO CONTAMINACION QUIMICA DEL AMBIENTE LUZ EDITH BARBA HO

5.1. VESILIND, P.A., PEIRCE J.J, Environmental Engineering Pollution and control Ann

Arbor Science Publishers. Second Edition, Michigan 1983.



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5.2. HORNE, R.A. The Chemistry of our Environmental John Wiley and Sons. Inc: Canada 1978.

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5.5. CRAIG, P.J. Organometallic compounds in the environmental principles and reactions. Longman Group Limited. England 1986.

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5.7. FORSTNER, U. Contaminated Sediments. Springer Verlag, Berlin 1989. 5.8. TORIBARA, T.Y. COLEMAN, J.R, Dahneke, B, Feldman I. Environmental Pollutants.

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England 1986. 5.14. THE CHEMICAL SOCIETY: Environmental Chemistry. Volume 1 Specialist

Periodical Reports, Burlington House, London WIV OBN, 1975. 5.15. ALBAIGES, J. Analytical Techniques in Environmental Chemistry. Pergamon

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Book Company 1968. 5.19. KIETH, L.H. Identification and Analysis of organic pollutants in water. Ann

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5.21. PURVES, D. Trace-element contamination of the environmental. Elsevier Scientific Publishing Company Amsterdam. 1977.

5.22. MICHALYNA, W. Land quality ass affected by the wastewater treatment lagoon and discarge route at st. Claude, Manitoba-Proc. Annu. Conv-West. Can water wastewater Assoc. 1991, 43, 117-21- Eng.

5.23. WUTTKE, G. Thober, B; Lieth, H. Simulation of nitrate transport in groundwater with a trhee-dimensional groundwater model run as a subroutine in an agroecosystem model. Ecol. Modell. 1991, 57 (3-4), 263-76. End.

5.24. RUIZ, E; ROMERO, F; BESGA, G. Selective Solubilization of heavy metals in torrential river sediments Toxicol. Environ. Chem. 1991, 33(1-2), 1-6. Eng.

5.25. KLOCHENKO, P.D; SAKEVICH, A.L. Peculiarities of the nitrate and nitrite acumulation in drinking water sources. Gig. Saint. 1991, (6), 17-20 Russ.

5.26. NYER, EVON K; KRAMER, VICTORIA, VALKENBURB, N. Biochemical effects on contaminant fate and transport. Ground-water monit. Rev. 1991, 11(2), 80-2 Eng.

5.27. MITRA, S.K., BRINKMANN, J.; PRUPPACHER, H.R. A wind tunnel study on the drop-to-particle conversion. J. Aerosol. Sci. 1992, 23 (3), 24556 Eng.

5.28. GLOVER, DAVID; HOPKE, P.; Vermette, S. Et all Source apportionment with site specific source profiles J. Air Waste Manage. Assoc. 1991, 43(1), 294-305 Eng.

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5.30. PETERSEN, RONALD; STUNBERG, K. Wind tunnel modeling for evaluating accidental spell of toxics chemicals Proc. Natl. Conf. Hazard. Wastes Harzard. Mater., 7th 1990, 475-80 Eng.

5.31. WIGLEY, T. A. A simple inverse carbon cycle model Global Biogeochem. Cycles 1991, 5(4), 373-82 Eng.

5.32. LINDELL, A. Acidity of airborne particles from residential wood burning. ..proc., Annv Meet.-Air Waste Manage. Assoc. 1991, 84(15A) Eng.

5.33. EDWARDS, G; KELLY, J,; MAYS, P. Ozone, acidic precipitation, and soil mangnesium impacts on soil and loblolly pine seedling nutrient status after three growing seasons. Water, air, soil pollut. 1992, 63 (3-4),281-94. Eng.

5.34. STREICH, M; LAVRMANN, G.; MEISTER, K. Special requirements for calculation methods for soil decontamination processes. Fluid. Phase Equilib.1991, 70(2-3), 165-73 Eng.

5.35. PETRUZELLI, D.; LOPEZ, A.; LIBERTI, L. PETIO, G. The land disposal of wastes. Envirom Sci. Res.1991,42(CPE) 675-89 Eng.

5.36. HERNANDEZ, L.; FERNANDEZ, M.; GONZALEZ, M. Organochlorine pollutants in water, soils and earthworms in the guadalquivir River. Spain. Bull. Environ. Contam.Toxicol. 1992, 49(2),192-8. Eng.



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5.37. BRODERSER,K; CHRISTIANSEN, H.; et al. Application of the Ecces model to forest soils. Dev. Environ. Modell 1990, 15,387-96 Eng.

5.38. TIMMONS, DALE M. In situ vitrificacion of mercuric arsenic, organocholorine pesticides and PCB-Bearing waste. PROC-A&WM ANNU MEET. 1990,83(1) Eng.

5.39. GRUEN, MANFRED; MACHELITT, B; Heavy Metal soil pollution load in the area freiber/saxony, Germany. WLB, Wasser Luft Boden 1991, 35(3),80-1 Ger.

5.40. ASANTE-DUAH, DANIEL K. A risk appraisal protocol for developing cleanup criteria in the restoration of contaminated sites PROC.IND.WASTE.CONF. 1990 45th, 45-58 Eng.

5.41. FELSOT, A; DZANTOR, E. Assessment of problems associated with landfilling or land application of pesticide waste and feasibility of cleanup by microbiological degradation. Gov. Rep. Announce, Index (U.S.) 1991, 91(5) Abs. No. 111,892.

5.42. GELBERT, G.; BOGUSLAWSKI, E.V. Soil and plant contamination with harmful substances after long timetrials of sewage sluge application on arable land and grassland. CONTAM. SOIL 90, INT. KFK/TNO. CONF. 3rd 1990, 1, 219-20 Eng.

5.43. FAUST S.D., ALY O.M., Chemistry of the natural wathers, butter worths. Stoneham, Ma. 1981.

5.44. HAMILTON F.L., SIMPSON G.S., Calculos de Quimica Analitica, Mc Graw Hill, New York1964.

5.45. SNOEYINK V.L., JENKINS D., Water Chemistry, John Wiley & Sons, New York 1980.

5.46. STUMM W. MORGAN J., Aquatic Chemistry, Wiley-Interscience, New York, 1970.

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5.48. LaGREGA, M.; et al. Gestin de Residuos Txicos, McGraw Hill, Madrid, 1996.

5.49. Dickson, T.R. Qumica Enfoque Ecologico, Limusa, Mxico, 2003. 5.50. Brown, T.; et al. Qumica la Ciencia Central, Pearson Prentice Hall, Mxico

2004. 5.51. Vallejo, M. C.; Baena, C.A. Toxicolog'ia Ambiental, Grupo empresarial Wills,

Colombia, 2007. 5.52. Eweis, J.; Et al. Principios de Biorecuperacion, McGraw Hill, Madrid, 1999.

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Química de La Contaminación Ambiental