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Annex
103
10 Annex 10.1 Cromatogrames de les proves realitzades a la part experimental. Per tal d’optimitzar el mètode d’extracció, tant la líquid –líquid com la en fase sòlida, es van fer un seguit de proves i en aquest punt es mostren els cromatogrames de les proves més característiques. 10.1.1 Cromatograma primera prova
Figura 1. Cromatograma aigua ST
RT: 5,99 - 40,96
10 15 20 25 30 35 40Time (min)
0
10
20
30
40
50
60
70
80
90
10027,12
24,6520,547,63 19,48 30,6721,64
18,59 36,9627,2917,37 40,5332,86 35,0325,7312,7612,448,28
NL:3,75E8TIC F: MS 1 NF_Sortida_01_100217183721
Annex
104
10.1.2 Cromatograma segona prova
Figura 2. Cromatograma aigua ST 10.1.3 Cromatograma tercera prova
Figura 3. Cromatograma aigua Font Vella
RT: 5,99 - 41,01
10 15 20 25 30 35 40Time (min)
0
10
20
30
40
50
60
70
80
90
100 27,13
14,22 22,61
20,55 24,6618,9428,2218,607,62 17,37 36,96 40,5333,2430,6825,7312,7712,44
9,88
NL:2,42E8TIC F: MS F_Sortida_01_100217171936
RT: 5,96 - 35,96
6 8 10 12 14 16 18 20 22 24 26 28 30 32 34Time (min)
0
10
20
30
40
50
60
70
80
90
10027,13
7,62
30,68
14,25
33,2532,71 35,5424,6618,95
14,3720,84 21,38 23,6617,55 30,5428,2214,628,27 26,2012,77 28,6119,0914,78 21,8917,177,18
10,999,89
NL:6,37E7TIC F: MS 3 FontVella1L01
Annex
105
10.1.4 Cromatograma quarta prova
Figura 4. Cromatograma aigua Mili-Q 10.1.5 Cromatograma cinquena prova
Figura 5. Cromatograma aigua Mili-Q
RT: 5,99 - 31,02
6 8 10 12 14 16 18 20 22 24 26 28 30Time (min)
0
10
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10028,62
27,12
7,54 14,21
22,60 24,6618,94 30,8520,8017,54 21,77 26,1914,39 28,4612,76 16,187,20 11,009,868,25
NL:3,57E8TIC F: MS 4 D_aigua01
RT: 5,99 - 31,01
6 8 10 12 14 16 18 20 22 24 26 28 30Time (min)
0
10
20
30
40
50
60
70
80
90
10027,12
7,6329,63
28,22
28,3824,66
18,9529,9021,3812,76 21,777,10 18,6016,04 19,0918,22 23,7915,9312,438,23 25,6911,25 12,89 20,91 22,04
NL:1,86E8TIC F: MS 8 SPE_MiliQ_Bomba_Membrana
Annex
106
10.1.6 Cromatogrames sisena prova
Figura 6.Cromatograma acetona
Figura 7. Cromatograma diclorometà
RT: 5,99 - 30,98
6 8 10 12 14 16 18 20 22 24 26 28 30Time (min)
0
10
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50
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100 7,67
27,126,95 30,6729,7429,0710,97 24,668,18 26,939,25 11,36 13,80 15,90 18,61 22,6116,94 21,5720,87
NL:4,41E8TIC F: MS acetona
RT: 5,99 - 31,02
6 8 10 12 14 16 18 20 22 24 26 28 30Time (min)
0
10
20
30
40
50
60
70
80
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10027,14
24,66
10,996,02 9,238,27 27,3811,11 29,7512,24 24,6121,5314,21 18,6114,68 25,5517,07 22,6219,55
NL:5,46E8TIC F: MS diclormeta
Annex
107
Figura 8. Cromatograma hexà
Figura 9. Cromatograma isooctà
RT: 5,99 - 36,03
6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36Time (min)
0
10
20
30
40
50
60
70
80
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100 32,76 35,7732,57
32,2131,92
31,6931,48
31,24
31,05
30,6830,59
30,40
29,7610,99 29,54
29,1627,87
27,696,11 6,55 8,24 26,9413,628,85 26,1311,21 13,80 18,2915,90 19,45 24,5120,28
NL:2,37E7TIC F: MS hexa
RT: 5,99 - 31,03
6 8 10 12 14 16 18 20 22 24 26 28 30Time (min)
0
10
20
30
40
50
60
70
80
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100 11,00
9,97
13,6330,876,24 30,096,59 28,62
13,778,29 9,50 28,2927,1322,6211,13 16,14 26,4212,06 24,6718,6413,97 21,7719,6717,78
NL:6,27E7TIC F: MS isoocta
Annex
108
10.1.7 Cromatograma setena prova
Figura 10. Cromatograma aigua Mili-Q
10.1.8 Cromatogrames vuitena prova a)
Figura 11. Cromatograma sense nitrogen
RT: 5,99 - 31,01
6 8 10 12 14 16 18 20 22 24 26 28 30Time (min)
0
10
20
30
40
50
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10027,19
24,66
21,5024,61 25,6622,61 28,62 29,6617,0614,21 18,14 19,5412,8411,008,276,08 8,80 15,68 20,12
NL:2,77E9TIC F: MS 9 liquid_liquid_MiliQ01
RT: 5,99 - 34,02
6 8 10 12 14 16 18 20 22 24 26 28 30 32 34Time (min)
0
10
20
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10027,31
7,65
21,05
24,828,276,5131,39
32,1212,81 28,8111,03 19,07 21,51 32,6422,3020,55 28,958,9718,52 23,73 25,3117,26
10,92 16,2915,0711,29
NL:9,82E7TIC F: MS 10 Blanc_N2_01_RES
Annex
109
Figura 12. Cromatograma nitrogen extra pur
Figura 13. Cromatograma nitrogen pur
RT: 5,99 - 34,00
6 8 10 12 14 16 18 20 22 24 26 28 30 32 34Time (min)
0
10
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100 27,31
7,60
6,55
8,27
24,8211,03 12,81
8,9831,1719,07 27,5721,52 31,3829,03
21,91 25,8710,92 19,3015,0611,22 18,5212,94 17,27 23,32
NL:7,74E7TIC F: MS 10 Blanc_N2_02_FORA
RT: 5,99 - 34,01
6 8 10 12 14 16 18 20 22 24 26 28 30 32 34Time (min)
0
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10027,31
7,66
24,82
12,81 27,5721,5319,08 29,65 31,3921,68 27,17 32,457,22 11,018,27 8,49 17,2712,94 16,29
NL:1,77E8TIC F: MS 10 Blanc_N2_03_DINS
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110
10.1.9 Cromatogrames novena prova
Figura 14. Cromatograma columna ISOLUTE
Figura 15. Cromatograma columna SUPELCO
RT: 5,99 - 39,01
6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38Time (min)
0
10
20
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10027,35
24,83
6,42 7,16 8,53 10,76 30,03 31,41 32,30 34,1211,08 35,71 38,0314,29 21,6818,7316,23 25,7422,77
NL:7,10E8TIC F: MS 11 ISOLUTE01
RT: 5,99 - 34,01
6 8 10 12 14 16 18 20 22 24 26 28 30 32 34Time (min)
0
10
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10027,31
8,27
18,786,0429,6624,838,06 8,82 10,73 10,94 30,8612,81 31,0314,28 29,3318,7215,67 19,09 21,98 25,7423,74
NL:2,60E8TIC F: MS 11 SUPELCO
Annex
111
Figura 16. Cromatograma columna STRATA
10.1.10 Cromatograma desena prova
Figura 17. Cromatograma aigua BA
RT: 5,99 - 33,99
6 8 10 12 14 16 18 20 22 24 26 28 30 32Time (min)
0
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10027,33
8,2724,83
21,928,07 27,53 29,5623,968,82 31,3921,6810,73 12,82 19,75 25,8718,71 31,6614,28 16,15
NL:5,87E8TIC F: MS 11 STRATA
RT: 6,01 - 39,03
8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38Time (min)
0
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10012,39
27,32
18,34
24,108,29 24,8223,716,08 28,2310,75 22,7618,7212,75 29,03 31,3825,7316,74 32,96 33,84 36,57
NL:6,39E8TIC F: MS 12 Anoxica_sal50g_
Annex
112
Figura 18. Cromatograma aigua BA a pH=1
10.1.11 Cromatograma onzena prova
Figura 19. Cromatograma aigua Scharlau
RT: 6,00 - 39,03
6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38Time (min)
0
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10027,31
15,39
12,408,50
8,32
10,38
15,5418,379,07 14,0810,88 17,35
6,62 24,8331,3818,71 32,1828,82 33,55 35,9622,63 37,4119,50 25,73
NL:1,67E8TIC F: MS 12 Anoxica_sal50g_pH2_
RT: 6,00 - 39,02
6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38Time (min)
0
10
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30
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50
60
70
80
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10028,11
27,54
38,9938,48
36,3135,1230,53 30,69 34,5530,1629,93
27,18
18,5726,886,12 6,78 20,618,23 26,369,20 11,15
22,3612,18 23,9113,87 16,32 18,73
NL:7,98E6TIC F: MS 16 aigua_SCHARLAB
Annex
113
10.1.12 Cromatograma dotzena prova
Figura 20. Cromatograma aigua Scharlau
10.1.13 Cromatograma tretzena prova
Figura 21. Cromatograma aigua Scharlau
RT: 5,99 - 39,01
6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38Time (min)
0
10
20
30
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50
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100 24,84
28,83 31,4118,45 21,96 32,2022,7714,22 18,73 28,35 32,368,286,63 10,75 11,61 30,02 35,9927,60 36,6717,18 19,6816,24
NL:2,32E8TIC F: MS 17 aigua_SCHARLAB_100323112720
RT: 6,00 - 39,03
6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38Time (min)
0
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100 27,32
24,83
31,39
8,2436,9435,3634,3530,3730,12
6,71 29,3310,738,03 8,7911,04 12,83
14,31 18,73 22,77 27,2117,1715,46 19,67 21,26
NL:2,50E7TIC F: MS 18_LL_aigua_SCHARLAB_diclormeta01
Annex
114
10.1.14 Cromatograma catorzena prova
Figura 22. Cromatograma aigua BO
10.1.15 Cromatograma quinzena prova
Figura 23. Cromatograma aigua DP
RT: 5,99 - 39,02
6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38Time (min)
0
10
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10027,32
7,60
12,41
22,6317,49 18,32 24,8320,6912,83 22,728,28 31,4021,8015,1710,89 27,8618,72 28,8225,917,12 23,52 32,31 35,9533,1210,44 36,67
NL:2,70E8TIC F: MS 20 Anoxica_SPE_01
RT: 6,00 - 39,03
6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38Time (min)
0
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10012,83
24,827,6222,83
11,49 20,64 24,7235,2310,94 19,36 24,00 25,39
22,6331,4017,4714,64 26,53 27,32 35,96
28,8213,74 15,15 18,97
30,5215,8910,34 36,237,24 8,31 32,50 36,4933,45
NL:2,97E8TIC F: MS 21A_Decantador_Primari01
Annex
115
10.1.16 Cromatograma setzena prova
Figura 24: cromatograma aigua BA
10.2 Taules obtingudes a partir dels cromatogrames A continuació es mostren les taules dels components que s’han trobat a cada cromatograma estudiat. Les substàncies que estan marcades de color blau representen els contaminants analitzats i la substàncies de color groc representen els patrons que s’han afegit per tal de mirar si la recuperació és bona. El segon antracè que apareix representa el del patró de recuperació. En els llocs on hi posa res es perquè en aquells punts es massa complicat trobar el component perquè hi ha molt pics sobreposats. A la primera columna de la taula s’hi mostra el component, a la segona el temps que surt en el cromatograma, la tercera són els pics característics de cada component i la quarta és el numero cas. Cada component té un número d’identificació per tal de poder saber de quin es tracta d’una manera molt més fàcil. 10.2.1 Mostra d’extracció líquid –líquid En aquest cas només es mostra la taula del decantador primari perquè com s’ha dit a les conclusions és millro fer l’extracció en fase sòlida que líquid – líquid. mostra DP Component temps pic cas benzene,methyl 6,06 65-91 108-88-3 ethene,tetrachloro 6,75 166-131 127-18-4 acetonyldimethylcarbinol 7,55 59-101 123-42-2 benzene,ethyl 8,05 91-106 100-41-4
RT: 5,99 - 39,01
6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38Time (min)
0
10
20
30
40
50
60
70
80
90
100 27,33
12,43
6,93
11,0010,53 12,868,5022,77 29,55
18,33 22,0710,407,47 17,49 27,45 32,3724,8315,84 20,6914,24 23,71 28,3525,91 30,02 36,839,00 33,03 33,97
NL:4,47E8TIC F: MS 23BA_anoxic
Annex
116
benzene,ethyl 8,27 91-106 100-41-4 p-xylene 8,31 91-106 106-42-3 p-xylene 8,51 91-106 106-42-3 o-xylene 8,8 91-106 95-47-6 ethanol,2-butoxy 9,1 57-87 111-76-2 3-pinanol,stereisomer 9,73 70-84 27779-29-9 2-propanol, 1-butoxy 9,88 57-87 5131-66-8 methylneopentylcarbinol 10,18 57-101 6144-93-0 toluene,m-ethhyl 10,31 105-120 620-14-4 4-decene 10,5 55-69 19689-18-0 Phenol 10,74 66-94 108-95-2 benzene,1,2,4-trimethyl 10,93 105-120 95-63-6 1,4-dichlorobenzene-d4 11,24 150-152 3855-82-1 1,2-dimethoxy-propane 11,34 59-73 7778-85-0 Mesitylene 11,48 105-120 108-67-8 2-propyl-1-penthanol 11,58 57-70 58175-57-8 Cineole 11,65 81-93 470-82-6
Cresol 12,39 107-79-77 106-44-5
Cresol 12,44 107-79-77 106-44-5
3,7-dimethyl-1,6-octadien-3-ol 12,83 71-93 78-70-6
benzeneethanol 13,07 91-92 60-12-8 Alcanfor 13,63 81-95 464-48-2 Borneol 13,87 95-110 507-70-0 Tetralin 13,9 104-132 119-64-2 Borneol 13,97 95-110 507-70-0 L-(-)-Menthol 14,08 71-81 2216-51-5 naphtalene-d8 14,21 136-108 1146-65-2 butoxyethoxyethanol 14,29 57-75 112-34-5 p-meth-1-en-8-ol,acetate 14,35 59-93 3-(3-oxo-tetrahydro-pyran-2-yl)-propionic acid, methyl ester 14,43 71-85 2-propylheptanol 14,65 57-71 21862-63-5 ethanol,2-phenoxy- 14,79 94-77 122-99-6 2-octen-1-ol,3,7-dimethyl 14,87 69-81 40607-46-5 1-propanol,1,1'-(propylenedioxy)di 15,07 59-103 1638-16-0 1-phenoxypropan-2-ol 15,15 59-94 770-35-4 tran-geraniol 15,26 69-93 106-24-1 3,3-dimehyl-1-(6-methyltetrahydro-2H-pyran-2-yl)-2-buanone 15,42 99-81
343947-11-5
1-decanol 15,5 55-56 112-30-1 8-hydroxy-tricyclo[5,2,1,0(2,6)]dec-3-ene 15,68 66-91 37275-49-3 isobornyl,acetate 15,81 95-121 125-12-2 Indole 15,88 90-117 120-72-9 1-propanol,1,1'-(propylenedioxy)di 16,07 59-103 1638-16-0
Annex
117
naphtalene,2-methyl 16,16 142-115 91-57-6 phenethyl,alcohol,a,a-dimethyl,acetate 16,22 117-132 151-05-3 2,2,4,4,6,8,8-Hptamethylnonane 16,29 57-71 4390-004-9 4-tert-butylcyclohexyl acetate 16,42 57-82 32210-23-4 1,2,3-propanetriol,diacetate 16,53 103-145 25395-31-7 p-meth-1-en-8-ol,acetate 16,64 121-93 80-26-2 2,2,4-trimethyl-1,3-pentanediol diisobutyrate 16,72 71-83 6846-50-0 4-tert-butylcyclohexyl acetate 16,92 57-82 32210-23-4 3-hydroxy-2,2,4-trimethylpentyl ester of isobutanoic acid 16,98 71-89 74367-34-3 indole, 3-methyl 17,18 103-130 83-34-1 n-tetradecane 17,25 57-71 629-59-4 diphenyl ether 17,38 170-77 101-84-8 2,4,7,9-tetramethyl-5-decyn-4,7-diol 17,48 109-151 126-86-3 Indan-1,3-diol monoacetate 17,66 66-117 Coumarín 17,91 118-146 91-64-5 1-(4-tert-butylphenyl)propan-2-one 17,97 147-175 81561-77-5 naphtalene,2-methoxy 18,05 115-158 93-04-9 1-undecanol 18,23 55-69 112-42-5 acenaftale d10 18,43 164-80 10567-26-2 propane, 1,3-bis (ocatadecyloxy) 18,53 57-281 17367-38-3 phenol,2,4-di-tert-butyl 18,72 191-57 96-76-4 Indan-1,3-diol monopropionate 18,88 66-132 naphtalene,2-ethoxy 18,97 115-144 93-18-5 2-(hydroxymethyl)-4-methylphenol 19,05 91-120 4383-007-7 dodecanoic acid 19,43 73-60 143-07-0 diethyl phthalate 19,76 149-177 84-66-2 1-(3,6,6-trimethyl-1,6,7,7a-tetrahydrocyclopenta[c]pyran-1-yl)ethanone 19,81 191-206 undecane, 5-phenyl 20,21 91-105 4537-015-9 tetracethylenediamine 20,29 72-127 10543-57-4 methyl dihydrojasmonate 20,43 83-156 24851-98-7 undecane, 3-phenyl 20,58 91-105 4537-87-2 cyclotetradecane 20,66 55-69 295-17-0 benzoic acid,2-hydroxy,hexyl ester 20,74 120-138 6259-76-3 heptadecane 20,89 57-71 629-78-7 undecane, 2-phenyl 20,99 91-105 4536-88-3 4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-methyl-3-buten-2-one 21,05 135-191 13743-21-0 ethanol, 2-(dodecyloxy)- 21,12 57-71 4536-30-5 dodecane, 6-phenyl 21,27 91-105 2719-62-2 dodecane, 5-phenyl 21,33 91-147 2719-63-3 dodecane, 4-phenyl 21,46 91-133 2719-64-4 octanal,2-(phenylmethylene) 21,52 117-129 101-86-0 myristic acid 21,67 73-60 544-63-8 Lauramide 21,76 59-72 1120-16-7
Annex
118
antracene d10 21,54 188-80 1719-06-8 antracene d10 22,07 188-80 1719-06-8 isopropyl myristate 22,25 102-288 110-27-0 tridecane, 6-phenyl 22,33 91-105 4534-49-0 tridecane, 5-phenyl 22,4 91-147 4534-50-3 tridecane, 4-phenyl 22,54 91-133 4534-51-4 alert-pep 22,65 109-194 58-08-2 Galoxolide 22,72 243-213 1222-05-5 phthalic acid, butyl isohexyl ester 22,77 149-223 hexadecen-1-ol, trans-9- 22,84 57-69 64437-47-4 Nonadecane 23,03 57-71 629-92-5 tridecane, 2-phenyl 23,19 91-105 4534-53-6 palmitic acid, methyl ester 23,28 74-87 112-39-0 palmitin,1,2-di 23,6 57-98 761-35-3 hexadecanoic acid 23,8 73-129 57-10-3
3,3-diheptyl-2-benzofuran-1(3H)-one 24,12 147-231 299420-15-8
hexadecanoic acid, 1-methylethyl ester 24,26 60-102 142-91-6 Oleanitrile 24,83 55-122 Triclosan 25,22 218-290 3380-34-5 oleic acid 25,53 55-69 112-80-1 oleic acid 25,69 55-69 112-80-1 adogen 73 27,38 59-72 301-02-0 1-butyl-3,4-dihydroisoquinoline 28,21 145-146 33351-43-8 chrysene-d12 28,36 120-240 1719-03-5 1-methylbutyl palmitate 28,43 256-257 55195-08-9 phthalic acid, 6-ethyloct-3-yl 2-ethylhexyl ester 28,83 149-167 all-trans-squalene 31,42 69-81 111-02-4 perylene-d12 32,26 264-132 1520-96-3 Res 35,31 Res 36,03 Res 36,26 Ergostanol 37,41 215-233 6538-002-9
Taula1.Compostos orgànics trobats en l’extracció líquid –líquid de la mostra DP
10.2.2 Mostres de l’extracció en fase sòlida A continuació es mostren les taules dels components que s’han trobat a cada cromatograma del decantador primari, de la bassa anòxica, de la bassa òxica i de la sortida. mostra DP Component temps pic cas 2,2,3-trimethylpentane 6,05 57-99 564-02-3 2,3,4-trimethylpentane 6,22 71-55 565-75-3
Annex
119
(2-methyloctyl)benzene 6,27 57-92 49826-80-4 benzene,methyl 6,46 65-91 108-88-3 (2Z)-3,4,4-trimethyl-2-pentene 6,72 97-55 39761-64-3 2,2,4,4-tetramethyltetrahydrofuran 6,96 55-113 3358-28-9 ethene,tetrachloro 7,24 166-13 127-18-4 2-tert-butyl-3-methyloxetane 7,5 70-55 7045-82-1
2-methylpentyl propionate 8,25 57-84 185756-33-6
ethylbenzene 8,35 91-106 100-41-4 p-xylene 8,51 91-106 106-42-3 2-(3,3-dimethylbutyl)oxirane 8,59 57-69 53907-77-0 o-xylene 9,01 91-106 95-47-6 n-nonane 9,18 57-85 111-84-2 2,6-dimethyloctane 9,87 57-71 2051-30-1 2-methyl-3-ethylheptane 10,01 57-98 14676-29-0 [(2-ethylhexyl)methyl]oxirane 10,02 57-70 2461-15-6 2,5,6-trimethyldecane 10,27 57-71 62108-23-0 2-methyl-1-decanol 10,29 57-69 18675-24-6 toluene,m-ethyl 10,41 105-120 620-14-4 2-methylnonane 10,45 57-71 871-83-0 Mesitylene 10,53 105-120 108-67-8 3,4-dimethyl-1-decene 10,58 57-71 50871-03-9 toluene,m-ethyl 10,75 105-120 620-14-4 toluene.o-ethyl 10,76 105-120 611-14-3 4-propyl-3-heptene 10,81 55-69 4485-13-6 cis-4-decene 10,82 55-69 19398-88-0 2,2,7,7-tetramethyloctane 10,96 57-85 1071-31-4 Mesitylene 11,01 105-120 108-67-8 n-decane 11,11 57-71 124-18-5 1,4-dichlorobenzene d4 11,32 115-150 3855-82-1 p-mentane,1,4-epoxy 11,41 111-71 470-67-7 benzene,m-diethyl 11,53 105-119 141-93-5 ethylhexanol 11,63 57-70 104-76-7 m-mentha-6,8-diene 11,66 68-93 1461-27-4 Cineole 11,71 93-108 470-82-6 3,7-dimethylnonane 11,82 57-71 17302-32-8 benzene,m-diethyl 12,01 105-119 141-93-5 toluene,m-propyl 12,04 105-134 1074-43-7 2-tolyloxirane 12,13 105-134 2783-26-8 p-xylene,2-ethyl 12,18 119-134 1758-88-9 benzene,m-diethyl 12,24 105-119 141-93-5 toluene,p-propyl 12,33 105-134 1074-55-1 2,6-dimethyl-7-octen-2-ol 12,38 59-82 18479-58-8 p-xylene,2-ethyl 12,5 119-134 1758-88-9 m-xylene,4-ethyl 12,52 119-134 874-41-9
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o-xylene,4-ethyl 12,64 119-134 934-80-5 styrene,3,4-dimethyl 12,68 117-132 27831-13-6 butylcellosolve acetate 12,69 57-87 112-07-2 m-xylene,4-ethyl 12,75 119-134 874-41-9 n-undecane 12,85 57-71 1120-21-4 1,3-diethyl-4-methylbenzene 12,94 119-133 1758-85-6 p-xylene,2-ethyl 12,99 119-134 1758-88-9 1-sec-butyl-4-methylbenzene 13,04 119-139 1595-16-0 5,9,9-trimethylspiro[3,5]nona-5,7-dien-1-one 13,15 119-134 91531-36-1 Durene 13,23 119-134 95-93-2 3,7-dimethyldecane 13,3 57-71 17312-54-8 p-menth-3-en-1-ol 13,45 81-93 586-82-3 p-menth-3-en-1-ol 13,62 81-93 586-82-3 Alcanfor 13,65 95-81 464-48-2 Isodurene 13,75 119-134 527-53-7 Borneol 13,85 95-110 10385-78-1 Tetralin 13,91 104-132 119-64-2 1-sec-butyl-4-methylbenzene 13,94 119-139 1595-16-0 borneol,(1S,2R,4S) 13,98 95-110 464-45-9 Menthol 14,06 71-85 1490-04-6 p-menth-1en-4-ol 14,16 71-111 20126-76-5 naphtalene-d8 14,22 136-108 1146-65-2 1-methylene-1H-indene 14,27 128-51 2471-84-3 p-menth-1-en-8-ol 14,35 59-121 10482-56-1 n-dodecane 14,42 57-71 112-40-3 cyclohexanol,1-methyl-4-(1-methylethylidene) 14,45 121-93 586-81-2 2-propylheptanol 14,64 57-71 1004-59-8 4-tert-butylcyclohexanol 14,68 57-81 21862-63-5 phenol,o-(2-methylallyl) 14,78 133-148 20944-88 1-propanol,2,2'-oxybis 15,06 59-103 108-61-2 1-propanol,1,1'-(propylenedioxy)di 15,14 59-103 1638-16-0 m-cresol,6-ethyl 15,36 121-136 1687-61-2 7-oxo-2-oxa-7-thiatricyclo[4,4,0,0(3,8)]decan-4-ol 15,42 83-139 8-hydroxy-tricyclo[5,2,1,0(2,6)]dec-3-ene 15,66 66-91 37275-49-3 Carvacrol 15,8 135-150 499-75-2 phenol,4-(1,1-dimethylethyl) 15,83 107-135 98-54-4 n-tridecane 15,88 57-71 629-50-5 tetrapropylene glycol,monomethyl ether 16,06 59-73 20324-34-9 naphtalene,2-methyl 16,18 142-115 91-57-6 phenethyl,alcohol,a,a-dimethyl,acetate 16,21 117-132 151-05-3 7-chloro-5-phenyl-1-(trimethylsilyl)-1,3-dihydro-2h-1,4-benzodiazepin 16,28 73-341
55299-224-6
4-octene-2,7-diol,2,7-dimethyl-Z 16,51 59-81 allo-ocimene 16,64 121-136 673-84-7 propanoic acid,2-methyl-2,2-dimethyl-1-(1-methylethyl)- 16,72 71-83 6846-50-0
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1,3-propanediyl ester 3-hydroxy-2,2,4-trimethylpentyl ester of isobutanoic acid 16,98 71-89 74367-34-3 glycine,N-[N-(N-glycylglycyl)glycyl] 17,16 114-71 637-84-3 n-tetradecane 17,25 57-71 629-59-4 diphenyl ether 17,38 57-170 101-84-8 Hexa-hydro-farnesol 17,69 57-69 6750-34-1 Hexa-hydro-farnesol 17,78 57-69 6750-34-1 2-methylhexadecan-1-ol 17,8 57-69 2490-48-4 Hexa-hydro-farnesol 17,87 57-69 6750-34-1 isotridecyl alcohol 17,97 69-71 27458-92-0 isotridecyl alcohol 18,06 69-71 27458-92-0 Hexa-hydro-farnesol 18,11 57-69 6750-34-1 3-heptadecanol 18,2 69-83 624-08-8 2,5-di-tert-butyl-p-quinone 18,23 205-220 2640-77-7
3-penten-2-one,4(2,6,6-trimethyl-2-cyclohexen-1-yl) 18,4 135-150 114933-28-7
acenaftale d10 18,44 164-80 10567-26-2 phenol,2,4-di-tert-butyl 18,71 191-57 96-76-4 2,4,6-triisopropylphenol 18,78 205-220 benzoic acid,p-ethoxy,ethyl ester 18,9 121-149 23676-09-7 2-methyl-1-dodecanol 18,96 57-71 57289-26-6 dethyl phthalate 19,75 149-177 84-66-2 methyl,p-tert-butylphenylacetate 19,79 131-191 3549-23-3 5-isopropyl-2,2,7a-trimethylhexahydro-1,3-benzodioxol-4-ol 20,27 153-213 75316-52-8 tetracethylenediamine 20,29 72-127 10543-57-4 methyl dihydrojasmonate 20,43 83-156 24851-98-7
ascaridole epoxide 20,53 69-135 135760-25-7
a-ionone,methyl 20,67 57-191 127-43-5 banzoic acid,2-hydroxy,hexyl ester 20,74 120-138 6259-76-3 ppentaethylene glycol 20,94 89-133 4792-15-8 acetic acid p-tert-butylphenyl ester 21,03 135-150 3056-64-2 2-ethyl-5-proppylphenol 21,13 135-149 72386-20-0 phenol,p-tert-pentyl 21,14 107-135 80-46-6 4-tert-octyl-o-cresol 21,19 149-220 2219-84-3 anisole,4,'-(1,2-diethylethylene)di 21,26 121-149 130-78-9 p-anisic acid, 4-nitrophenyl ester 21,37 135-77 4-tert-octyl-o-cresol 21,46 149-220 2219-84-3 p-anisic acid, 4-nitrophenyl ester 21,55 135-77 dibenzyl phthalate 21,67 91-107 523-31-9 benzeneacetonitrile,4-(1,2,3,6-tetrahydro-4-pyridinyl) 21,79 129-198 antracene d10 21,94 188-80 1719-06-8 antracene d10 22,07 188-80 1719-06-8 alert-pep 22,63 109-194 58-08-2 Galoxolide 22,72 243-213 1222-05-5
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phthalic acid, diisobutyl ester 22,76 149-223 84-69-5 7-acetyl-6-ethyl-1,1,4,4,-tetramethyltetralin 22,82 243-258 88-29-9 camphor-10-sulfonyl chloride 22,91 109-151 21286-54-4 Res 23,08 palmitic acid, methyl ester 23,28 74-87 112-39-0 4-([2-(dimethylamino)-2-oxoethyl]amino)-N,N-diethylbenzamide 23,5 205-277 92728-05-7 5,6,7-trimehoxy-1-indanone 23,59 207-222 38472-90-1 phthalic acid butyl 2-pentyl ester 23,71 149-223 ethanol,2-[2-(4-nonylphenoxy)ethoxy] 23,78 193-135 20427-84-3 1,4-methanoazulen-7(1H)-one,octahydro-1,5,5,8a-tetramethyl 23,9 164-94 65437-70-9 1-methyl-3-phenyl-1H_indole 24,02 165-207 30020-98-5 hydroquinone-2,5-tert-pentyl 24,07 221-250 79-74-3 methyl-4-(2-methyl-1,3-dioxolan-2-yl)phenyl ether 24,19 135-179 36881-00-2 Res 24,6 cyclic octaatomic sulfur 24,7 64-256 10544-50-0 Oleanitrile 24,83 55-122 Res 24,88 Triclosan 25,23 218-290 3380-34-5 2-ethylhexyl,tran-4-methoxycinnamate 25,63 161-178 83834-69-7
1,8-naphthalenediol,2,7-diacetyl-3,6-dimethyl 25,9 257-239 100198-05-8
adogen 73 27,33 59-72 301-02-0 carbamazepen 27,5 193-236 298-46-4 triphenyl phosphate 27,73 77-326 115-86-6 chrysene-d12 28,33 120-240 1719-03-5 bis(2-ethyhexyl)phthalate 28,81 149-167 117-81-7 all-trans-squalene 31,38 69-81 111-02-4 epicholestanol 35,2 233-388 516-95-0 Res 35,96
Taula2.Compostos orgànics trobats en l’extracció en fase sòlida de la mostra DP Mostra BA Component Temps Pic cas 2,3- dithiabutane 6,1 94-79 624-92-0 2,3,4- trimetil pentane 6,15 71-55 565-75-3 Toluene 6,4 91-92 108-88-3 Butyric acid, 2-methyl-, methyl ester 6,61 57-88 868-57-5
Methyl neopentyl ketone 6,64 57-58-114 590-50-1
(2Z)-3,4,4-trimethyl-2-pentene 6,67 97-55 39761-64-3 5-methyl-3-heptanol 6,74 59-83 18720-65-5 2,2,4,4-tetramethyltetrahydrofuran 6,93 113-55 3358-28-9 ethene, tetrachloro 7,22 166-164 127-18-4
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2-tert-butyl-3-methyloxetane 7,47 55-70 7045-82-1 2,2-dimethyl-5-hexen-3-ol 8,23 69-87 19550-89-1 ethylbenzene 8,32 91-106 100-41-4 o-xylene 8,5 91-106 106-42-3 1-nonen-3-ol 8,56 57-72 21964-44-3 p-xylene 9 91-106 106-42-3 methyl caproate 9,69 74-87 106-70-7 1-hexyl-2-methylcyclopropane 9,83 56-69 62238-09-9 1-pentanol,2,4,4-trimethyl 10,11 57-98 16325-63-6 n-propilbenze 10,24 91-120 103-65-1 toluene m-ethyl 10,4 105-120 620-80-8 trisulfide, dimethyl 10,52 126-79 3658-80-8 toluene, o -ethyl 10,75 105-120 611-14-3 3-octene,4-ethyl 10,8 55-69 53966-51-1 cis-4-decene 10,82 55-69 19398-88-0 2,2,7,7 tetramethyloctane 10,94 55-69 10171-31-4 Hemimellitene 10,99 105-120 526-73-8 1,4-dichlorobenzene-d4 11,3 115-150 2199-69-1 Mesitylene 11,52 105-120 108-67-8 toluene, m-ethyl 11,55 105-120 620-14-4 ethylhexanol 11,62 57-70 104-76-7 Cineole 11,7 93-108 470-82-6 Indane 11,77 117-58 496-11-7 benzene, m-diethyl 12,01 119-105 141-33-5 toluene,m-propyl 12,04 77-105 1074-43-7 benzene, m-diethyl 12,12 119-105 141-33-5 p-xylene, 2-ethyl 12,17 119-134 1758-88-9 benzene, m-diethyl 12,22 119-105 141-33-5 benzene, p-diethyl 12,24 105-119 105-05-5 toluene, p-propyl 12,31 105-134 1074-55-1 m-cresol 12,43 79-109 108-39-4 0-xylene, 3ethyl 12,53 119-134 933-98-2 o-xylene, 4 ethyl 12,63 119-134 934-80-5 Undecane 12,86 57-71 1120-21-4 o-xylene, 4 ethyl 12,99 119-134 934-80-5 phenol, o (2-methylallyl) 13,14 133-148 20944-88-1 o-xylene, 4 ethyl 13,16 119-134 934-80-5 Durene 13,24 119-134 95-93-2 Prehnitene 13,25 119-134 488-23-3 Camphor 13,65 95-108 76-22-2 Alcanfor 13,67 95-81 464-48-2 idan,5 methyl 13,72 117-132 874-35-1 Prehnitene 13,76 119-134 488-23-3 Tetralin 13,91 104-132 119-64-2
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cyclohexene,3-isobutyl 14,07 81-95 4104-56-7 L-(-) menthol 14,09 71-81 2216-51-5 naphtalene-d8 14,24 136-108 1146-65-2 Azulene 14,28 128-102 275-51-4 Dodecane 14,44 57-71 112-40-3 6-methyloctadecane 14,46 57-71 10544-96-4 4-tert-butylcyclohexanol 14,71 57-81 21862-63-5 dimethyl tetrasulphide 14,77 79-158 5756-24-1 propanol, oxybis 15,09 59-103 25265-71-8 1-propanol-2,2'-exybis 15,15 59-103 108-61-2 Tricyclo[5.2.1.0(2,6)]dec-3-en-10-one 15,7 66-79 fenol,4(1,1-dimethylethyl) 15,85 135-107 98-54-4 Indolizine 15,91 117-90 274-40-8 naphtalene,2-methyl 16,17 142-115 91-57-6 1-(82-hydroxyethyl)3-methyl malonate 16,58 101-59 131072-41-8 2,2-dimethyl-1-(2-hydroxy-1-isopropyl)propyl ester of isobutanoic acid 16,74 71-89 74367-33-2 2-(3-isopropylphenyl)-1-propanol 16,78 163-91 54518-11-5 2-ethyl-3-hydroxyhexyl 2-methylpropanoate 17 89-71 74367-31-0 hexandecen-1-ol, trans-9 17,17 55-69 64437-47-4 benzene, 1,1' oxybis 17,39 170-51 101-84-8 2,4,7,9-tetramethyl-5-decyne-4,7-diol 17,41 109-151 126-86-3 phenol,2,6-ditert-butyl 17,89 57-191 128-39-2 2,4,4,6,6,8,8-heptamethyl-1-nonene 17,91 113-97 15796-04-0 2,5-di-tert-butyl-p-quinone 18,25 205-220 2460-77-7 1,3-dihydroindol-2-one 18,33 104-133 59-48-3 acenaphtene-d10 18,46 164-80 15067-26-2 phenol,2,4-di-tert-butyl 18,73 57-191 96-76-4 4,4,5,7,8- pentamethyl-6 chromanol 18,79 205-220 50442-70-1 benzoic acid,p-ethoxy, ethyl ester 18,92 121-149 23676-09-7 isomethyl-a-ionol 19,12 109-119 70172-00-8 5-butyl-5-isobutylthiophene 19,31 153-196 54845-35-1 1,2-benzendicarboxylic acid, diethyl ester 19,76 149-177 84-66-2 7,9-dihydroxy-6,9a -dimethyl-3-methylenedecahydroazuleno[4,5-b]furan-2(3H)one 19,8 194-230 20555-03-7 4(p-chlorophenyl)-6-ethoxy-(4-h,-5h,-6h-)-oxin-3-carboxaldehyde 20,07 72-192 84735-34-4 a-lonone, methyl 20,69 57-191 127-43-5 5-(7a-isopropenyl-4,5-dimethyl-octahydroinden-4-yl)-3-methyl-pent-2-enal 20,77 95-191 Coronopilin 21,03 113-123 2571-81-5 5-(7a-isopropenyl-4,5-dimethyl-octahydroinden-4-yl)-3-methyl-pent-2-enal 21,05 95-191 5-(7a-isopropenyl-4,5-dimethyl-octahydroinden-4-yl)-3-methyl-pent-2-enal 21,21 95-191 Fenretinide 21,46 109-135 65646-68-6 deoxyspergualin 21,67 72-86
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anthracene-d10 21,96 188-80 1719-06-8 anthracene-d10 22,08 188-80 1719-06-8 Galoxolide 22,72 218-243 1222-05-5 phthalic acid, diisobutyl ester 22,77 149-223 84-69-5 ethanone, 1(3-ethyl-5,6,7,8-tetrahydro-5,5,8,8- tetramethyl-2-naphthalenyl 22,83 243-258 88-29-2
1-(2,8,8-trimethyl-5,6,7,8-tetrahydro-4H-cyclohepta[b]furan-5-yl)ethanone 23,51 205-177 71596-88-8 phthalic acid, 6-ethyl-3-octyl butyl ester 23,72 149-223 cyclic octaatomic sulfur 24,72 64-256 10544-50-0 Oleanitrile 24,83 55-122 Triclosan 25,21 218-290 3380-34-5 Olean-12-ene-3a,16a,21a,22a,24,28-hexanol 25,38 175-215 20853-07-0 2,4,6,8,9-pentathiaadamantane-3-methanol-a,a,1,5,6-penta methyl 25,51 59-143 21404-63-7 tetrapropylene glycol, monomethyl ether 25,54 59-73 20324-34-9 Palmitamide 25,73 59-72 629-54-9 phenol, 4,4' isopropylidenedi 25,83 213-228 80-05-7 1,8-nahphtalenediol,2,7-diacetyl-3,6-dimethyl 25,91 239-257 100198-05-8 Triethylene glycol monododecyl ether 26,52 57-89 3055-94-5 Hexaethylene glycol mono-n-dodecylether 27,22 89-133 3055-96-7 adogen 73 27,33 59-72 301-02-0 tetrapropylene glycol, monomethyl ether 27,45 59-73 20324-34-9 tetrapropylene glycol, monomethyl ether 27,54 59-73 20324-34-9 TPP 27,73 77-326 115-86-6 Chrysene d12 28,35 240-120 1719-03-5 (1s,14s)-bicyclo[12.10.0+-3,6,9,12,15,18,21,24-octaoxatetracosane 29,47 73-87 136982-93-9 Cannabinol, o-trimethylsilyl 30,53 367-310 64846-18-0 1,2-propanediol,3-(hexadecyloxy)-diacetate 32,11 57-71 21994-82-1 Olean-12-ene-3a,16a,21a,22a,24,28-hexanol 32,25 175-215 20853-07-0 Olean-12-ene-3a,16a,21a,22a,24,28-hexanol 32,36 175-215 20853-07-0
Taula3.Compostos orgànics trobats en l’extracció en fase sòlida de la mostra BA Mostra BO Component temps pic cas disulfide,dimethyl 6,01 94-79 624-92-0 2,3,4-trimethylpentane 6,07 71-55 565-75-3 2,3,4- trimethylhexane 6,13 57-71 921-47-1 Toluene 6,33 91-65 108-88-3 z-3,4,4-trimethyl-2-pentene 6,61 97-55 39761-64-3 tetrachloroethylene 7,15 131-166 127-18-4 Hexane,2,3,5-trimethyl 7,45 85-57 1069-53-0 dimethylsiloxane cyclic trimer 7,49 207-96 541-05-9
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acetonyldimethylcarbinol 7,84 59-101 123-42-2 ethylbenzene 8,29 91-106 100-41-4 p-xylene 8,46 91-106 106-42-3 o-xylene 8,96 91-106 95-47-6 1,8-nonadien-3-ol 9,8 84-57 159010-02-3 Toluene,m-ethyl 10,36 105-120 620-14-4 Diemthyl trisulfide 10,5 126-79 3658-80-8 Toluene,o-ethyl 10,72 105-120 611-14-3 2,6-dimethyl-3-octene 10,78 55-69 6874-28-8 2,2,7,7-Tetramethyloctane 10,93 57-85 1071-31-4 Mestylene 10,98 105-120 108-67-8 1,4-diclorobenzene d4 11,28 150-115 3855-82-1 Hydratropic 11,3 105-150 7782-26-5 Mestylene 11,51 105-120 108-67-8 Ethylhexanol 11,59 57-70 104-76-7 Cineole 11,68 93-108 470-82-6 benzene,p-diethyl 11,99 105-119 105-05-5 Toluene,m-propyl 12,01 105-134 1074-43-7 p-xylene,2-ethyl 12,15 119-134 1758-88-9 benzene,p-diethyl 12,21 105-119 105-05-5 2-methyldecane 12,23 57-71 6975-98-0 toluene,p-propyl 12,3 105-124 1074-55-1 1-(3-methyl-3-butenyl)-4-methylbenzene 12,32 105-160 56818-01-0 p-cresol 12,42 77-107 106-44-5 m-cresol 12,5 107-108 108-39-4 m-cresol 12,61 107-108 108-39-4 Undecane 12,82 57-71 1120-21-4 1,2-dimethyl-3-vinyl-1,4-cyclohexandiene 12,96 91-119 62338-57-2 o-xylene,3-ethyl 12,98 119-134 933-98-2 phenol,4-(2-propenyl) 13,13 134-107 501-92-8 o-xylene,4-ethil 13,15 119-134 934-80-5 o-xylene,4-ethil 13,21 119-134 934-80-5 Alcanfor 13,65 95-81 464-48-2 Isodurene 13,75 119-134 527-53-7 Tetralin 13,9 104-132 119-64-2 2-phenylbutanal 13,92 91-119 2439-43-2 naphthalene-d8 14,22 108-136 1146-65-2 n-dodecane 14,43 57-71 112-40-3 dimethyl tetrasulphide 14,78 79-158 5756-24-1 phenol,p-tert-butyl 15,83 107-135 98-54-4 n-tridecane 15,9 57-71 629-50-5 Indole 15,91 117-90 120-72-9 naphtalene,2-methyl 16,17 142-115 91-57-6 n-Tetradecene 17,16 55-57 1120-36-1 2,4,7,9-Tetramethyl-5-decyne-4,7-diol 17,48 109-151 126-86-3
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phenol,2,6-di-tert-butyl 17,88 191-57 128-39-2 disulfide,bis(1,1,3,3-tetramethylbutyl) 17,89 57-113 29956-99-8 Res 18,25 4-methylindoline 18,33 133-104 62108-16-1 1,3-dihydroindol-2-one 18,35 104-133 59-48-3 acentracene-d10 18,42 164-80 1506726-2 2-methyl-5-[1-(5-methyl-2-furyl)ethyl]furan 18,66 175-190 3209-79-8 2,4-ditert-butylphenyl-5-hydroxypentanoate 18,71 191-206 166273-38-7 phenol,2,4-bis(1,1-dimethylethyl)-6-methyl 18,78 205-220 616-55-7 benzoic acid,p-ethoxy, ethyl ester 18,91 121-149 23676-09-7 isomethyl-a-ionol 19,11 109-119 70172-00-8 1,2-benzenedicarboxylic acid,diethyl ester 19,74 149-177 84-66-2 2-(methylmercapto)benzothiazole 19,94 148-181 615-22-5 N-hydroxytetradecanamide 20,06 211-57 17698-03-2 Lenthionine 20,33 78-142 292-46-6 a-Ionone, methyl 20,67 57-191 127-43-5 Res 21,04 Res 21,13 Res 21,53 Res 21,67 Res 21,79 anthracene-d10 21,94 188-80 1719-06-8 anthracene-d10 22,07 188-80 1719-06-8 Galoxolide 22,71 243-213 1222-05-5 phthalic acid, isobutyl 4-octyl ester 22,76 149-223 cyclic octaatomic sulfur 23,15 64-256 10544-50-0 cyclic octaatomic sulfur 23,32 64-256 10544-50-0 Galoxolide 23,33 243-213 1222-05-5 phenol,2,4-bis(1,1-dimethylpropyl) 23,5 205-71 120-95-6 dibutyl phthalate 23,7 149-223 84-74-2 cyclic octaatomic sulfur 24,01 64-256 10544-50-0 cyclic octaatomic sulfur 24,15 64-256 10544-50-0 cyclic octaatomic sulfur 24,28 64-256 10544-50-0 Oleantrile 24,83 55-122 Triclosan 25,22 218-290 3380-34-5 olean-12-ene-3a,16a,21a,22a,24,28-hexanol 25,38 191-264 20853-07-0 pydridine-2-carbohydrazide,N2-[1-(4-ethylphenyl)ethylidene) 25,81 252-106 293760-26-6 methyl podocarpa-8(14)9(11),12-trien-15-oate 25,91 197-257 108395-86-4 fyrol fr2 27,17 75-99 13674-87-8 adogen 73 27,3 59-72 301-02-0 chrysene-d12 28,34 240-120 1719-03-5 perylene-d12 32,34 264-132 1520-96-3
Taula4.Compostos orgànics trobats en l’extracció en fase sòlida de la mostra BO
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mostra ST component temps pic Cas 2,2,3-trimethylpentane 6,08 57-99 564-02-3 2,3,4-trimethylpentane 6,24 71- 565-75-3 Toluene 6,48 91-92 108-88-3 z-3,4,4-trimethyl-2-pentene 6,75 55-97 39761-64-3 2,2,4,4-tetramethyltetrahydrofuran 6,99 55-113 3358-28-9 2,4-dimethylhexane 7,09 57-85 589-43-5 ethene,tetrachloro 7,26 131-166 127-18-4 2-tert-butyl-3-methyloxetane 7,53 55-70 7045-82-1 ethylbenzene 8,37 91-106 100-41-4 p-xylene 8,54 91-106 106-42-3 o-xylene 9,04 91-106 95-47-6 1-methylpentyl cyclopropane 9,86 56-69 6976-28-9 Toluene, p-ethyl 10,42 105-120 622-96-8 3-nonene,3-methyl-E 10,6 55-69 69405-42-1 cis-4-decene 10,83 55-69 19398-88-0 2,2,7,7-tetramethyloctane 10,98 57-71 1071-31-4 n-decane 11,14 57-71 124-18-5 1,4-dichlorobenzene d4 11,32 115-150 3855-82-1 2,2,4,4-tetramethyloctane 11,67 57-99 62183-79-3 Cineole 11,73 93-108 470-82-6 Farnesan 11,81 57-71 3891-98-3 2,6-dimethylnonane 12,05 57-71 17302-28-2 n-undecane 12,86 57-71 1120-21-4 naphthalene-d8 14,24 136-108 1146-65-2 n-dodecane 14,46 57-71 112-40-3 4-methyldodecane 15,91 71-85 6117-97-1 naphtalene,2-methyl 16,19 142-115 91-57-6 alcanfor 13,68 95-81 464-48-2 tetradecyl chloroacetate 17,17 83-97 18277-86-6 2,4,7,9-tetramethyl-5-decyne-4,7-diol 17,5 109-151 126-86-3 a-lonone,methyl 17,91 57-191 127-43-5 res 18,24 acenaphthene d10 18,45 162-80 15067-26-2 cashmeran 18,72 135-191 33704-61-9 phenol2,6-bis(1,1-dimethylethyl)-4-methyl 18,79 57-205 128-37-0 res 19,11 1,3-cyclohexanedione,4,6-di-t-butyl 19,42 57-83 diethyl phthalate 19,76 149-177 84-66-2 ethyl citrate 20,48 115-157 77-93-0 a-lonone,methyl 20,69 57-191 127-43-5 a-lonone,methyl 20,76 57-191 127-43-5 res 21,05 cedran-diol,8S,14 21,51 93-189 62600-05-9
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benzeneacetonitrile,4-(1,2,3,6-tetrahydro-4-pyridinyl) 21,8 129-198 anthracene-d10 21,96 188-80 1719-06-8 anthracene-d10 22,08 188-80 1719-06-8 galoxolide 22,72 213-243 1222-05-5 7-acetyl-6-ethyl-1,1,4,4-tetramethyltetralin 22,84 243-258 88-29-9 2,4,6-triisoppropylphenetole 23 205-248 3224-45-0 galoxolide 23,34 213-243 1222-05-5 1,3-dimethyl-5,7-di--n-propyladamantane 23,52 107-205
benzonitrile,4-(1-octynyl) 23,94 140-168 312708-98-8
p-benzoquinone,2,5-di-tert-pentyl 24,01 177-248 4584-63-8 2-methyldipyrrolo[1,2-1,2',1'-c]pyrazine-3-carbonitrile 24,28 195-140 oleanitrile 24,84 55-122 triclosan 25,23 218-290 3380-34-5 triacontane 25,74 57-71 638-68-8
methyl podocarpa-8(14)9(11)12-trien-15-oate 25,92 197-257 108395-86-4
adogen-73 27,33 59-72 301-02-0 triphenyl phosphate 27,73 326-77 115-86-6 chrysene d12 28,36 120-240 1719-03-5 perylene-d12 32,25 132-264 1520-96-3
Taula7.Compostos orgànics trobats en l’extracció en fase sòlida de la mostra ST
