Rango de pH Rango de pHHMnO2(-a) HMnO2(-a)MnO(a) -2 8.9 Mn(+2a) -2Mn(+2a) 8.9 16 MnO(a) 8.15MnO2(-2a) MnO2(-2a) 15.8MnOH(+a) MnOH(+a)

Rango de pHRango de pH H2S 0

H2S 0 7.3 HS- 7.05

181614121086420

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1.5

1.0

0.5

0.0

-0.5

-1.0

-1.5

-2.0

5

5

5 55 5

S - H2O - System at 5.00 C

C:\HSC6\EpH\S25595.iep pH

Eh (Volts)

H 2 O limits

H2S(a) HS(-a) S(-2a)

ELEMENTS Molality PressureS 1.000E-02 1.000E+00

181614121086420

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25

25

25 2525 25

S - H2O - System at 25.00 C

C:\HSC6\EpH\S25595.iep pH

Eh (Volts)

H 2 O limits

H2S(a) HS(-a) S(-2a)

ELEMENTS Molality PressureS 1.000E-02 1.000E+00

1614121086420-2

2.0

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0.0

-0.5

-1.0

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-2.0

Mn - H2O - System at 5.00 C

C:\HSC6\EpH\Mn5.iep pH

Eh (Volts)

H 2 O L imits

Mn(+2a)MnO(a)

ELEMENTS Molality PressureMn 1.000E+00 1.000E+00

1614121086420-2

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0.0

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Mn - H2O - System at 25.00 C

C:\HSC6\EpH\Mn5.iep pH

Eh (Volts)

H 2 O L imits

Mn(+2a) MnO(a) MnO2(-2a)

ELEMENTS Molality PressureMn 1.000E-04 1.000E+00

HS- 7.3 13.5 S-2 12.9S-2 13.5 18

Rango de pH Rango de pHH2CO3 -2 6.5 H2CO3 -2HCO3- 6.5 10.5 HCO3- 6.35CO3= 10.5 14 CO3= 10.2

1614121086420-2

2.0

1.5

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-1.0

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-2.0

C - H2O - System at 25.00 C

C:\HSC5\EpH\C5.iep pH

Eh (Volts)

H 2 O L imits

CO3(-2a)H2CO3(a) HCO3(-a)

ELEMENTS Molality PressureC 1.000E-03 1.000E+00

1614121086420-2

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C - H2O - System at 5.00 C

C:\HSC5\EpH\C5.iep pH

Eh (Volts)

H 2 O L imits

CO3(-2a)H2CO3(a) HCO3(-a)

ELEMENTS Molality PressureC 1.000E-03 1.000E+00

Rango de pHHMnO2(-a)

8.15 Mn(+2a) -2 6.815.8 MnO(a) 6.8 13.5

16 MnO2(-2a) 13.5 16MnOH(+a)

Rango de pH7.05 H2S 0 6.712.9 HS- 7.05 11.4

181614121086420

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25 2525 25

S - H2O - System at 25.00 C

C:\HSC6\EpH\S25595.iep pH

Eh (Volts)

H 2 O limits

H2S(a) HS(-a) S(-2a)

ELEMENTS Molality PressureS 1.000E-02 1.000E+00

181614121086420

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95

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95 9595 95

S - H2O - System at 95.00 C

C:\HSC6\EpH\S25595.iep pH

Eh (Volts)

H 2 O limits

H2S(a) HS(-a) S(-2a)

ELEMENTS Molality PressureS 1.000E-02 1.000E+00

1614121086420-2

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Mn - H2O - System at 25.00 C

C:\HSC6\EpH\Mn5.iep pH

Eh (Volts)

H 2 O L imits

Mn(+2a) MnO(a) MnO2(-2a)

ELEMENTS Molality PressureMn 1.000E-04 1.000E+00

1614121086420-2

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Mn - H2O - System at 95.00 C

C:\HSC6\EpH\Mn5.iep pH

Eh (Volts)

H 2 O L imits

Mn(+2a) MnO(a) MnO2(-2a)

ELEMENTS Molality PressureMn 1.000E-04 1.000E+00

18 S-2 11.4 18

Rango de pH6.35 H2CO3 -2 6.0510.2 HCO3- 6.05 10.05

16 CO3= 10.05 16

1614121086420-2

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C - H2O - System at 25.00 C

C:\HSC5\EpH\C5.iep pH

Eh (Volts)

H 2 O L imits

CO3(-2a)H2CO3(a) HCO3(-a)

ELEMENTS Molality PressureC 1.000E-03 1.000E+00

1614121086420-2

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C - H2O - System at 95.00 C

C:\HSC5\EpH\C5.iep pH

Eh (Volts)

H 2 O L imits

CO3(-2a)H2CO3(a) HCO3(-a)

ELEMENTS Molality PressureC 1.000E-03 1.000E+00

# reacciones1 Mn(+2a) + H2O(l) = MnOH(+a) + H(+a)2 Mn(+2a)+H2O(l)=MnO(a)+2H(+a)3 MnO(a)+H2O(l)=HMnO2(-a)+H(+a)4 MnOH(+a)=MnO(a)+H(+a)

Mn(OH)4(-2a)

# reacciones

Mn(+2a) + H2S(a) = MnS + 2H(+a)Mn(+2a) + HS(-a) = MnS + H(+a)MnOH(+a) + HS(-a) = MnS + H2OHMnO2(-a) + HS(-a) + 2H(+a) = MnS + 2H2OMn(OH)4(-2a) + S(-2a) + 4H(+a) = MnS + 4H2O

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95 9595 95

S - H2O - System at 95.00 C

C:\HSC6\EpH\S25595.iep pH

Eh (Volts)

H 2 O limits

H2S(a) HS(-a) S(-2a)

ELEMENTS Molality PressureS 1.000E-02 1.000E+00

1614121086420-2

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1.5

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Mn - H2O - System at 95.00 C

C:\HSC6\EpH\Mn5.iep pH

Eh (Volts)

H 2 O L imits

Mn(+2a) MnO(a) MnO2(-2a)

ELEMENTS Molality PressureMn 1.000E-04 1.000E+00

# reacciones

Mn(+2a) + H2CO3(a) = MnCO3 + 2H(+a)Mn(+2a) + HCO3(-a) = MnCO3 + H(+a)MnOH(+a) + CO3(-2a) + H(+a) = MnCO3 + H2OHMnO2(-a) + CO3(-2a) + 3H(+a) = MnCO3 + 2H2OMn(OH)4(-2a) + CO3(-2a) + 4H(+a) = MnCO3 + 4H2O

1614121086420-2

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C - H2O - System at 95.00 C

C:\HSC5\EpH\C5.iep pH

Eh (Volts)

H 2 O L imits

CO3(-2a)H2CO3(a) HCO3(-a)

ELEMENTS Molality PressureC 1.000E-03 1.000E+00

EspeciaciónEspecie DeltaS (J/mol.K)DeltaG (Kj/mol)Mn(+2a) -73.638 -227.997

H2O 69.95 -237.141Mn(OH)2 99 -615.783

H(+a) 0 0MnOH(+a) 1.255 -407.036

Mn(OH)4(-2a)HMnO2(-a) -38.074 -506.097MnO2(-2a) -63.597 -429.032H2CO3(a) 187.443 -623.197MnCO3 105.6 -809.919

HCO3(-a) 98.45 -586.865CO3(-2a) -49.999 -527.907

H2S(a) 125.5 -28.6MnS 78.199 -218.347

HS(-a) 68.199 12.082S(-2a) -14.602 85.972

Mn(+2a)+H2O(l)=MnOH(+a)+H(+a) Mn(+2a) + H2O(l) = MnO(a) + 2H(+a)T deltaH deltaS deltaG K Log(K) TC kJ J/K kJ C

0 59.814 5.756 58.242 7.27E-12 -11.138 05 59.84 5.85 58.212 1.17E-11 -10.933 5

10 59.819 5.777 58.183 1.84E-11 -10.734 1015 59.762 5.579 58.155 2.86E-11 -10.543 1520 59.679 5.292 58.128 4.38E-11 -10.358 2025 59.576 4.944 58.102 6.61E-11 -10.18 2530 59.46 4.557 58.078 9.82E-11 -10.008 3035 59.335 4.148 58.057 1.44E-10 -9.842 3540 59.205 3.73 58.037 2.08E-10 -9.682 4045 59.072 3.311 58.019 2.98E-10 -9.527 4550 58.939 2.894 58.004 4.20E-10 -9.377 5055 58.805 2.482 57.99 5.87E-10 -9.232 5560 58.67 2.073 57.979 8.10E-10 -9.091 6065 58.535 1.674 57.97 1.11E-09 -8.955 6570 58.405 1.289 57.962 1.50E-09 -8.824 7075 58.277 0.921 57.957 2.01E-09 -8.696 7580 58.155 0.571 57.953 2.68E-09 -8.573 8085 58.037 0.24 57.951 3.53E-09 -8.453 8590 57.925 -0.07 57.95 4.61E-09 -8.336 9095 57.82 -0.358 57.952 5.98E-09 -8.223 95

100 57.722 -0.623 57.954 7.71E-09 -8.113 100

Formula FM Conc. Amount Amount Volume Formulag/mol wt-% mol g l or ml

Mn(+2a) 54.938 75.306 1 54.938 0 ml Mn(+2a)H2O(l) 18.015 24.694 1 18.015 18.069 ml H2O(l)

g/mol wt-% mol g l or mlMnOH(+a) 71.945 98.618 1 71.945 0 ml MnO(a)H(+a) 1.008 1.382 1 1.008 0 ml H(+a)

Predominancia 5°C

pH1

K 1.5Mn(+2a)+H2O(l)=MnOH(+a)+H(+a) 1.17E-11 2Mn(+2a) + H2O(l) = MnO(a) + 2H(+a) 2.47E-18 2.5MnO(a) + H2O(l) = HMnO2(-a) + H(+a) 1.37E-19 3MnOH(+a) = MnO(a) + H(+a) 2.11E-07 3.5

44.55

5.56

6.57

7.58

8.59

9.510

10.511

11.512

12.513

13.514

14.515

15.516

16.517

17.518

Predominancia 25°CK

Mn(+2a)+H2O(l)=MnOH(+a)+H(+a) 6.61E-11Mn(+2a) + H2O(l) = MnO(a) + 2H(+a) 3.66E-17MnO(a) + H2O(l) = HMnO2(-a) + H(+a) 1.16E-18MnOH(+a) = MnO(a) + H(+a) 5.54E-07

Predominancia 95°CK

Mn(+2a)+H2O(l)=MnOH(+a)+H(+a) 5.98E-09Mn(+2a) + H2O(l) = MnO(a) + 2H(+a) 3.27E-14MnO(a) + H2O(l) = HMnO2(-a) + H(+a) 2.81E-16MnOH(+a) = MnO(a) + H(+a) 5.47E-06

Mn(+2a) + H2O(l) = MnO(a) + 2H(+a) MnO(a) + H2O(l) = HMnO2(-a) + H(+a)deltaH deltaS deltaG K Log(K) T deltaHkJ J/K kJ C kJ

94.794 3.752 93.769 1.17E-18 -17.933 0 73.92794.155 1.435 93.756 2.47E-18 -17.608 5 73.84193.537 -0.767 93.754 5.05E-18 -17.297 10 73.73292.938 -2.863 93.763 1.00E-17 -16.998 15 73.60292.357 -4.863 93.783 1.94E-17 -16.712 20 73.45291.793 -6.772 93.812 3.66E-17 -16.437 25 73.28391.244 -8.596 93.85 6.73E-17 -16.172 30 73.09590.711 -10.341 93.898 1.21E-16 -15.918 35 72.88890.192 -12.01 93.954 2.12E-16 -15.673 40 72.66489.688 -13.607 94.018 3.65E-16 -15.437 45 72.42189.199 -15.135 94.089 6.17E-16 -15.21 50 72.16288.723 -16.595 94.169 1.02E-15 -14.991 55 71.88488.262 -17.989 94.255 1.66E-15 -14.78 60 71.58987.814 -19.324 94.349 2.66E-15 -14.575 65 71.278

87.38 -20.598 94.448 4.19E-15 -14.378 70 70.94986.961 -21.811 94.554 6.49E-15 -14.188 75 70.60186.557 -22.964 94.666 9.92E-15 -14.003 80 70.23486.168 -24.058 94.784 1.50E-14 -13.825 85 69.84885.794 -25.093 94.907 2.23E-14 -13.652 90 69.44185.438 -26.069 95.035 3.27E-14 -13.485 95 69.01385.098 -26.984 95.168 4.75E-14 -13.323 100 68.562

FM Conc. Amount Amount Volume Formula FMg/mol wt-% mol g l or ml g/mol

54.938 75.306 1 54.938 0 ml MnO(a) 70.93718.015 24.694 1 18.015 18.069 ml H2O(l) 18.015

g/mol wt-% mol g l or ml g/mol70.937 97.237 1 70.937 0 ml HMnO2(-a) 87.945

1.008 2.763 2 2.016 0 ml H(+a) 1.008

[H+] [Mn+2] [MnOH]+ [MnO] [HMnO2]- [Mn+2] Total %[Mn+2] %[PMnOH]+

MnO(a) + H2O(l) = HMnO2(-a) + H(+a) MnOH(+a) = MnO(a) + H(+a)deltaS deltaG K Log(K) T deltaH deltaSJ/K kJ C kJ J/K

-95.322 99.964 7.63E-20 -19.118 0 34.98 -2.004-95.633 100.441 1.37E-19 -18.864 5 34.315 -4.415

-96.02 100.92 2.40E-19 -18.619 10 33.718 -6.544-96.475 101.402 4.14E-19 -18.383 15 33.176 -8.442-96.991 101.885 6.99E-19 -18.156 20 32.678 -10.154-97.564 102.372 1.16E-18 -17.937 25 32.217 -11.715-98.191 102.861 1.88E-18 -17.725 30 31.785 -13.153-98.866 103.354 3.01E-18 -17.521 35 31.376 -14.489-99.589 103.85 4.74E-18 -17.324 40 30.988 -15.741

-100.356 104.35 7.35E-18 -17.134 45 30.616 -16.918-101.166 104.853 1.12E-17 -16.95 50 30.26 -18.029-102.017 105.361 1.69E-17 -16.773 55 29.918 -19.077

-102.91 105.874 2.50E-17 -16.601 60 29.593 -20.062-103.837 106.39 3.67E-17 -16.436 65 29.279 -20.998-104.804 106.912 5.30E-17 -16.276 70 28.976 -21.887

-105.81 107.439 7.57E-17 -16.121 75 28.684 -22.732-106.855 107.97 1.07E-16 -15.971 80 28.402 -23.535-107.941 108.507 1.49E-16 -15.827 85 28.131 -24.299-109.069 109.05 2.06E-16 -15.687 90 27.869 -25.023

-110.24 109.598 2.81E-16 -15.552 95 27.618 -25.71-111.456 110.152 3.80E-16 -15.421 100 27.377 -26.361

Conc. Amount Amount Volume Formula FM Conc.wt-% mol g l or ml g/mol wt-%

79.747 1 70.937 0 ml MnOH(+a) 71.945 10020.253 1 18.015 18.069 ml g/mol wt-%

wt-% mol g l or ml MnO(a) 70.937 98.59998.867 1 87.945 0 ml H(+a) 1.008 1.401

1.133 1 1.008 0 ml

%[MnO] %[HMnO2]- log[Mn+2] log[MnOH]+ log[MnO] log[HMnO2]- A1 A3

deltaG K Log(K)kJ

35.527 1.61E-07 -6.79435.543 2.11E-07 -6.67535.571 2.74E-07 -6.56335.608 3.50E-07 -6.45535.655 4.43E-07 -6.354

35.71 5.54E-07 -6.25735.772 6.85E-07 -6.16435.841 8.40E-07 -6.07635.917 1.02E-06 -5.99235.998 1.23E-06 -5.91136.086 1.47E-06 -5.83336.179 1.74E-06 -5.75936.276 2.05E-06 -5.68836.379 2.40E-06 -5.6236.486 2.79E-06 -5.55436.598 3.23E-06 -5.49136.714 3.71E-06 -5.43136.833 4.24E-06 -5.37236.956 4.83E-06 -5.31637.083 5.47E-06 -5.26237.214 6.17E-06 -5.21

Amount Amount Volumemol g l or ml

1 71.945 0 mlmol g l or ml

1 70.937 0 ml1 1.008 0 ml

LOG([Mn+2] Total)

Mn(+2a)+H2CO3(a)=MnCO3+2H(+a)T deltaH deltaS deltaG K Log(K)C kJ J/K kJ

5 24.049 -35.584 33.947 4.21E-07 -6.37615 25.209 -31.485 34.282 6.10E-07 -6.21525 26.229 -28.004 34.579 8.74E-07 -6.05935 27.191 -24.832 34.843 1.24E-06 -5.90745 28.142 -21.793 35.076 1.74E-06 -5.75955 29.106 -18.809 35.279 2.42E-06 -5.61665 30.088 -15.863 35.452 3.34E-06 -5.47775 31.106 -12.897 35.596 4.56E-06 -5.34185 32.169 -9.885 35.71 6.19E-06 -5.20995 33.287 -6.807 35.793 8.34E-06 -5.079

100 33.87 -5.236 35.824 9.66E-06 -5.015

Formula FM Conc. Amount Amount Volumeg/mol wt-% mol g l or ml

Mn(+2a) 54.938 46.97 1 54.938 0 mlH2CO3(a) 62.025 53.03 1 62.025 0 ml

g/mol wt-% mol g l or mlMnCO3 114.947 98.277 1 114.947 31.067 mlH(+a) 1.008 1.723 2 2.016 0 ml

K1 4.21E-07K2 1.32E+00 [CO3]-2 0.001K3 4.01E+21K4 1.39E+47K5

Mn(+2a)+HCO3(-a)=MnCO3+H(+a) MnOH(+a)+CO3(-2a)+H(+a)=MnCO3+H2OT deltaH deltaS deltaG K Log(K) TC kJ J/K kJ C

5 13.234 49.864 -0.636 1.32E+00 0.119 515 15 56.108 -1.167 1.63E+00 0.212 1525 16.431 60.99 -1.754 2.03E+00 0.307 2535 17.7 65.179 -2.385 2.54E+00 0.404 3545 18.916 69.062 -3.056 3.18E+00 0.502 4555 20.128 72.813 -3.766 3.98E+00 0.599 5565 21.348 76.474 -4.512 4.98E+00 0.697 6575 22.616 80.172 -5.295 6.23E+00 0.795 7585 23.955 83.961 -6.116 7.80E+00 0.892 8595 25.38 87.886 -6.975 9.77E+00 0.99 95

100 26.132 89.915 -7.42 1.09E+01 1.039 100

Formula FM Conc. Amount Amount Volume Formulag/mol wt-% mol g l or ml

Mn(+2a) 54.938 47.379 1 54.938 0 ml MnOH(+a)HCO3(-a) 61.017 52.621 1 61.017 0 ml CO3(-2a)

g/mol wt-% mol g l or ml H(+a)MnCO3 114.947 99.131 1 114.947 31.067 mlH(+a) 1.008 0.869 1 1.008 0 ml MnCO3

H2O

MnOH(+a)+CO3(-2a)+H(+a)=MnCO3+H2O HMnO2(-a)+CO3(-2a)+3H(+a)=MnCO3+2H2OdeltaH deltaS deltaG K Log(K) T deltaHkJ J/K kJ C kJ

-67.236 171.826 -115.03 4.01E+21 21.604 5 -175.393-62.17 189.731 -116.841 1.52E+21 21.182 15 -168.948

-57.844 204.495 -118.814 6.57E+20 20.817 25 -163.344-53.908 217.482 -120.925 3.16E+20 20.5 35 -158.172-50.147 229.494 -123.16 1.67E+20 20.222 45 -153.184

-46.46 240.904 -125.513 9.57E+19 19.981 55 -148.263-42.823 251.821 -127.977 5.90E+19 19.77 65 -143.38-39.155 262.512 -130.549 3.88E+19 19.588 75 -138.44-35.417 273.098 -133.227 2.71E+19 19.432 85 -133.395-31.577 283.672 -136.011 1.99E+19 19.299 95 -128.208-29.608 288.984 -137.442 1.74E+19 19.241 100 -125.547

FM Conc. Amount Amount Volume Formula FMg/mol wt-% mol g l or ml g/mol

71.945 54.11 1 71.945 0 ml HMnO2(-a) 87.94560.009 45.132 1 60.009 0 ml CO3(-2a) 60.009

1.008 0.758 1 1.008 0 ml H(+a) 1.008g/mol wt-% mol g l or ml g/mol

114.947 86.451 1 114.947 31.067 ml MnCO3 114.94718.015 13.549 1 18.015 19.646 ml H2O 18.015

HMnO2(-a)+CO3(-2a)+3H(+a)=MnCO3+2H2OdeltaS deltaG K Log(K)J/K kJ

271.874 -251.014 1.39E+47 47.143294.648 -253.851 1.05E+46 46.021313.774 -256.895 1.03E+45 45.011330.838 -260.12 1.25E+44 44.097346.768 -263.508 1.85E+43 43.267361.998 -267.053 3.26E+42 42.513376.656 -270.746 6.70E+41 41.826391.054 -274.585 1.59E+41 41.201405.338 -278.567 4.28E+40 40.631419.622 -282.692 1.30E+40 40.113426.802 -284.808 7.44E+39 39.872

Conc. Amount Amount Volumewt-% mol g l or ml

58.25 1 87.945 0 ml39.747 1 60.009 0 ml

2.003 3 3.024 0 mlwt-% mol g l or ml

76.135 1 114.947 31.067 ml23.865 2 36.03 39.292 ml

Mn(+2a)+H2CO3(a)=MnCO3+2H(+a)T deltaH deltaS deltaG K Log(K)C kJ J/K kJ

5 24.049 -35.584 33.947 4.21E-07 -6.37615 25.209 -31.485 34.282 6.10E-07 -6.21525 26.229 -28.004 34.579 8.74E-07 -6.05935 27.191 -24.832 34.843 1.24E-06 -5.90745 28.142 -21.793 35.076 1.74E-06 -5.75955 29.106 -18.809 35.279 2.42E-06 -5.61665 30.088 -15.863 35.452 3.34E-06 -5.47775 31.106 -12.897 35.596 4.56E-06 -5.34185 32.169 -9.885 35.71 6.19E-06 -5.20995 33.287 -6.807 35.793 8.34E-06 -5.079

100 33.87 -5.236 35.824 9.66E-06 -5.015

Formula FM Conc. Amount Amount Volumeg/mol wt-% mol g l or ml

Mn(+2a) 54.938 46.97 1 54.938 0 mlH2CO3(a) 62.025 53.03 1 62.025 0 ml

g/mol wt-% mol g l or mlMnCO3 114.947 98.277 1 114.947 31.067 mlH(+a) 1.008 1.723 2 2.016 0 ml

Mn(+2a)+HCO3(-a)=MnCO3+H(+a) MnOH(+a)+CO3(-2a)+H(+a)=MnCO3+H2OT deltaH deltaS deltaG K Log(K) TC kJ J/K kJ C

5 13.234 49.864 -0.636 1.32E+00 0.119 515 15 56.108 -1.167 1.63E+00 0.212 1525 16.431 60.99 -1.754 2.03E+00 0.307 2535 17.7 65.179 -2.385 2.54E+00 0.404 3545 18.916 69.062 -3.056 3.18E+00 0.502 4555 20.128 72.813 -3.766 3.98E+00 0.599 5565 21.348 76.474 -4.512 4.98E+00 0.697 6575 22.616 80.172 -5.295 6.23E+00 0.795 7585 23.955 83.961 -6.116 7.80E+00 0.892 8595 25.38 87.886 -6.975 9.77E+00 0.99 95

100 26.132 89.915 -7.42 1.09E+01 1.039 100

Formula FM Conc. Amount Amount Volume Formulag/mol wt-% mol g l or ml

Mn(+2a) 54.938 47.379 1 54.938 0 ml MnOH(+a)HCO3(-a) 61.017 52.621 1 61.017 0 ml CO3(-2a)

g/mol wt-% mol g l or ml H(+a)MnCO3 114.947 99.131 1 114.947 31.067 mlH(+a) 1.008 0.869 1 1.008 0 ml MnCO3

H2O

MnOH(+a)+CO3(-2a)+H(+a)=MnCO3+H2O HMnO2(-a)+CO3(-2a)+3H(+a)=MnCO3+2H2OdeltaH deltaS deltaG K Log(K) T deltaHkJ J/K kJ C kJ

-67.236 171.826 -115.03 4.01E+21 21.604 5 -175.393-62.17 189.731 -116.841 1.52E+21 21.182 15 -168.948

-57.844 204.495 -118.814 6.57E+20 20.817 25 -163.344-53.908 217.482 -120.925 3.16E+20 20.5 35 -158.172-50.147 229.494 -123.16 1.67E+20 20.222 45 -153.184

-46.46 240.904 -125.513 9.57E+19 19.981 55 -148.263-42.823 251.821 -127.977 5.90E+19 19.77 65 -143.38-39.155 262.512 -130.549 3.88E+19 19.588 75 -138.44-35.417 273.098 -133.227 2.71E+19 19.432 85 -133.395-31.577 283.672 -136.011 1.99E+19 19.299 95 -128.208-29.608 288.984 -137.442 1.74E+19 19.241 100 -125.547

FM Conc. Amount Amount Volume Formula FMg/mol wt-% mol g l or ml g/mol

71.945 54.11 1 71.945 0 ml HMnO2(-a) 87.94560.009 45.132 1 60.009 0 ml CO3(-2a) 60.009

1.008 0.758 1 1.008 0 ml H(+a) 1.008g/mol wt-% mol g l or ml g/mol

114.947 86.451 1 114.947 31.067 ml MnCO3 114.94718.015 13.549 1 18.015 19.646 ml H2O 18.015

HMnO2(-a)+CO3(-2a)+3H(+a)=MnCO3+2H2OdeltaS deltaG K Log(K)J/K kJ

271.874 -251.014 1.39E+47 47.143294.648 -253.851 1.05E+46 46.021313.774 -256.895 1.03E+45 45.011330.838 -260.12 1.25E+44 44.097346.768 -263.508 1.85E+43 43.267361.998 -267.053 3.26E+42 42.513376.656 -270.746 6.70E+41 41.826391.054 -274.585 1.59E+41 41.201405.338 -278.567 4.28E+40 40.631419.622 -282.692 1.30E+40 40.113426.802 -284.808 7.44E+39 39.872

Conc. Amount Amount Volumewt-% mol g l or ml

58.25 1 87.945 0 ml39.747 1 60.009 0 ml

2.003 3 3.024 0 mlwt-% mol g l or ml

76.135 1 114.947 31.067 ml23.865 2 36.03 39.292 ml

Mn(+2a)+H2CO3(a)=MnCO3+2H(+a)T deltaH deltaS deltaG K Log(K)C kJ J/K kJ

5 24.049 -35.584 33.947 4.21E-07 -6.37615 25.209 -31.485 34.282 6.10E-07 -6.21525 26.229 -28.004 34.579 8.74E-07 -6.05935 27.191 -24.832 34.843 1.24E-06 -5.90745 28.142 -21.793 35.076 1.74E-06 -5.75955 29.106 -18.809 35.279 2.42E-06 -5.61665 30.088 -15.863 35.452 3.34E-06 -5.47775 31.106 -12.897 35.596 4.56E-06 -5.34185 32.169 -9.885 35.71 6.19E-06 -5.20995 33.287 -6.807 35.793 8.34E-06 -5.079

100 33.87 -5.236 35.824 9.66E-06 -5.015

Formula FM Conc. Amount Amount Volumeg/mol wt-% mol g l or ml

Mn(+2a) 54.938 46.97 1 54.938 0 mlH2CO3(a) 62.025 53.03 1 62.025 0 ml

g/mol wt-% mol g l or mlMnCO3 114.947 98.277 1 114.947 31.067 mlH(+a) 1.008 1.723 2 2.016 0 ml

Mn(+2a)+HCO3(-a)=MnCO3+H(+a) MnOH(+a)+CO3(-2a)+H(+a)=MnCO3+H2OT deltaH deltaS deltaG K Log(K) TC kJ J/K kJ C

5 13.234 49.864 -0.636 1.32E+00 0.119 515 15 56.108 -1.167 1.63E+00 0.212 1525 16.431 60.99 -1.754 2.03E+00 0.307 2535 17.7 65.179 -2.385 2.54E+00 0.404 3545 18.916 69.062 -3.056 3.18E+00 0.502 4555 20.128 72.813 -3.766 3.98E+00 0.599 5565 21.348 76.474 -4.512 4.98E+00 0.697 6575 22.616 80.172 -5.295 6.23E+00 0.795 7585 23.955 83.961 -6.116 7.80E+00 0.892 8595 25.38 87.886 -6.975 9.77E+00 0.99 95

100 26.132 89.915 -7.42 1.09E+01 1.039 100

Formula FM Conc. Amount Amount Volume Formulag/mol wt-% mol g l or ml

Mn(+2a) 54.938 47.379 1 54.938 0 ml MnOH(+a)HCO3(-a) 61.017 52.621 1 61.017 0 ml CO3(-2a)

g/mol wt-% mol g l or ml H(+a)MnCO3 114.947 99.131 1 114.947 31.067 mlH(+a) 1.008 0.869 1 1.008 0 ml MnCO3

H2O

MnOH(+a)+CO3(-2a)+H(+a)=MnCO3+H2O HMnO2(-a)+CO3(-2a)+3H(+a)=MnCO3+2H2OdeltaH deltaS deltaG K Log(K) T deltaHkJ J/K kJ C kJ

-67.236 171.826 -115.03 4.01E+21 21.604 5 -175.393-62.17 189.731 -116.841 1.52E+21 21.182 15 -168.948

-57.844 204.495 -118.814 6.57E+20 20.817 25 -163.344-53.908 217.482 -120.925 3.16E+20 20.5 35 -158.172-50.147 229.494 -123.16 1.67E+20 20.222 45 -153.184

-46.46 240.904 -125.513 9.57E+19 19.981 55 -148.263-42.823 251.821 -127.977 5.90E+19 19.77 65 -143.38-39.155 262.512 -130.549 3.88E+19 19.588 75 -138.44-35.417 273.098 -133.227 2.71E+19 19.432 85 -133.395-31.577 283.672 -136.011 1.99E+19 19.299 95 -128.208-29.608 288.984 -137.442 1.74E+19 19.241 100 -125.547

FM Conc. Amount Amount Volume Formula FMg/mol wt-% mol g l or ml g/mol

71.945 54.11 1 71.945 0 ml HMnO2(-a) 87.94560.009 45.132 1 60.009 0 ml CO3(-2a) 60.009

1.008 0.758 1 1.008 0 ml H(+a) 1.008g/mol wt-% mol g l or ml g/mol

114.947 86.451 1 114.947 31.067 ml MnCO3 114.94718.015 13.549 1 18.015 19.646 ml H2O 18.015

HMnO2(-a)+CO3(-2a)+3H(+a)=MnCO3+2H2OdeltaS deltaG K Log(K)J/K kJ

271.874 -251.014 1.39E+47 47.143294.648 -253.851 1.05E+46 46.021313.774 -256.895 1.03E+45 45.011330.838 -260.12 1.25E+44 44.097346.768 -263.508 1.85E+43 43.267361.998 -267.053 3.26E+42 42.513376.656 -270.746 6.70E+41 41.826391.054 -274.585 1.59E+41 41.201405.338 -278.567 4.28E+40 40.631419.622 -282.692 1.30E+40 40.113426.802 -284.808 7.44E+39 39.872

Conc. Amount Amount Volumewt-% mol g l or ml

58.25 1 87.945 0 ml39.747 1 60.009 0 ml

2.003 3 3.024 0 mlwt-% mol g l or ml

76.135 1 114.947 31.067 ml23.865 2 36.03 39.292 ml

Mn(+2a)+H2S(a)=MnS+2H(+a)T deltaH deltaS deltaG K Log(K)C kJ J/K kJ

5 48.709 35.394 38.864 5.02E-08 -7.29915 47.335 30.54 38.535 1.03E-07 -6.98625 46.103 26.337 38.251 1.99E-07 -6.70235 44.981 22.634 38.006 3.61E-07 -6.44345 43.953 19.35 37.797 6.22E-07 -6.20655 43.004 16.412 37.618 1.03E-06 -5.98965 42.115 13.744 37.468 1.63E-06 -5.78875 41.29 11.337 37.342 2.49E-06 -5.60385 40.525 9.173 37.24 3.70E-06 -5.43295 39.823 7.237 37.158 5.34E-06 -5.273

100 39.495 6.353 37.124 6.35E-06 -5.197

Formula FM Conc. Amount Amount Volumeg/mol wt-% mol g l or ml

Mn(+2a) 54.938 61.719 1 54.938 0H2S(a) 34.076 38.281 1 34.076 0

g/mol wt-% mol g l or mlFormula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or mlMn(+2a) 54.938 61.719 1 54.938 0H2S(a) 34.076 38.281 1 34.076 0

g/mol wt-% mol g l or mlMnS 86.998 97.735 1 86.998 21.75H(+a) 1.008 2.265 2 2.016 0

Z

Mn(+2a)+HS(-a)=MnS+H(+a) MnOH(+a)+HS(-a)=MnS+H2OT deltaH deltaS deltaG K Log(K) TC kJ J/K kJ C

5 18.618 70.107 -0.882 1.47E+00 0.166 515 20.771 77.717 -1.623 1.97E+00 0.294 1525 22.506 83.638 -2.431 2.67E+00 0.426 2535 24.026 88.654 -3.293 3.62E+00 0.558 3545 25.456 93.223 -4.203 4.90E+00 0.69 4555 26.856 97.554 -5.157 6.62E+00 0.821 5565 28.239 101.707 -6.153 8.92E+00 0.951 6575 29.654 105.832 -7.191 1.20E+01 1.079 7585 31.126 109.998 -8.27 1.61E+01 1.206 8595 32.674 114.261 -9.391 2.15E+01 1.333 95

100 33.484 116.445 -9.968 2.49E+01 1.395 100

Formula FM Conc. Amount Amount Volume Formulag/mol wt-% mol g l or ml

Mn(+2a) 54.938 62.425 1 54.938 0 ml MnOH(+a)HS(-a) 33.068 37.575 1 33.068 0 ml HS(-a)

g/mol wt-% mol g l or mlMnS 86.998 98.855 1 86.998 21.75 ml MnSH(+a) 1.008 1.145 1 1.008 0 ml H2O

MnOH(+a)+HS(-a)=MnS+H2O HMnO2(-a)+HS(-a)+2H(+a)=MnS+2H2OdeltaH deltaS deltaG K Log(K) T deltaHkJ J/K kJ C kJ

-41.222 64.257 -59.095 1.26E+11 11.099 5 -149.378-38.992 72.138 -59.778 6.88E+10 10.837 15 -145.77

-37.07 78.695 -60.533 4.04E+10 10.606 25 -142.57-35.309 84.506 -61.35 2.51E+10 10.4 35 -139.573-33.616 89.912 -62.222 1.65E+10 10.217 45 -136.654-31.949 95.072 -63.147 1.13E+10 10.053 55 -133.752-30.296 100.034 -64.123 8.05E+09 9.906 65 -130.853-28.623 104.911 -65.147 5.96E+09 9.775 75 -127.907-26.911 109.758 -66.221 4.56E+09 9.659 85 -124.89-25.146 114.619 -67.343 3.60E+09 9.556 95 -121.777-24.238 117.068 -67.922 3.23E+09 9.509 100 -120.177

FM Conc. Amount Amount Volume Formula FMg/mol wt-% mol g l or ml g/mol

71.945 68.511 1 71.945 0 ml HMnO2(-a) 87.94533.068 31.489 1 33.068 0 ml HS(-a) 33.068

g/mol wt-% mol g l or ml H(+a) 1.00886.998 82.845 1 86.998 21.75 ml g/mol18.015 17.155 1 18.015 19.646 ml MnS 86.998

H2O 18.015

HMnO2(-a)+HS(-a)+2H(+a)=MnS+2H2OdeltaS deltaG K Log(K)J/K kJ

164.306 -195.08 4.34E+36 36.638177.055 -196.788 4.74E+35 35.676187.974 -198.615 6.30E+34 34.799197.862 -200.544 9.94E+33 33.997207.186 -202.57 1.83E+33 33.261216.167 -204.687 3.84E+32 32.585224.869 -206.892 9.16E+31 31.962233.452 -209.184 2.44E+31 31.388241.998 -211.561 7.21E+30 30.858250.569 -214.024 2.34E+30 30.369254.885 -215.288 1.38E+30 30.139

Conc. Amount Amount Volumewt-% mol g l or ml

71.483 1 87.945 0 ml26.878 1 33.068 0 ml

1.638 2 2.016 0 mlwt-% mol g l or ml

70.714 1 86.998 21.75 ml29.286 2 36.03 39.292 ml

Mn(+2a)+H2S(a)=MnS+2H(+a)T deltaH deltaS deltaG K Log(K)C kJ J/K kJ

5 48.709 35.394 38.864 5.02E-08 -7.29915 47.335 30.54 38.535 1.03E-07 -6.98625 46.103 26.337 38.251 1.99E-07 -6.70235 44.981 22.634 38.006 3.61E-07 -6.44345 43.953 19.35 37.797 6.22E-07 -6.20655 43.004 16.412 37.618 1.03E-06 -5.98965 42.115 13.744 37.468 1.63E-06 -5.78875 41.29 11.337 37.342 2.49E-06 -5.60385 40.525 9.173 37.24 3.70E-06 -5.43295 39.823 7.237 37.158 5.34E-06 -5.273

100 39.495 6.353 37.124 6.35E-06 -5.197

Formula FM Conc. Amount Amount Volumeg/mol wt-% mol g l or ml

Mn(+2a) 54.938 61.719 1 54.938 0H2S(a) 34.076 38.281 1 34.076 0

g/mol wt-% mol g l or mlFormula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or mlMn(+2a) 54.938 61.719 1 54.938 0H2S(a) 34.076 38.281 1 34.076 0

g/mol wt-% mol g l or ml

Mn(+2a)+HS(-a)=MnS+H(+a)T deltaH deltaS deltaG K Log(K)C kJ J/K kJ

5 18.618 70.107 -0.882 1.47E+00 0.16615 20.771 77.717 -1.623 1.97E+00 0.29425 22.506 83.638 -2.431 2.67E+00 0.42635 24.026 88.654 -3.293 3.62E+00 0.55845 25.456 93.223 -4.203 4.90E+00 0.6955 26.856 97.554 -5.157 6.62E+00 0.82165 28.239 101.707 -6.153 8.92E+00 0.95175 29.654 105.832 -7.191 1.20E+01 1.07985 31.126 109.998 -8.27 1.61E+01 1.20695 32.674 114.261 -9.391 2.15E+01 1.333

100 33.484 116.445 -9.968 2.49E+01 1.395

Formula FM Conc. Amount Amount Volumeg/mol wt-% mol g l or ml

Mn(+2a) 54.938 62.425 1 54.938 0 mlHS(-a) 33.068 37.575 1 33.068 0 ml

g/mol wt-% mol g l or mlMnS 86.998 98.855 1 86.998 21.75 mlH(+a) 1.008 1.145 1 1.008 0 ml

MnOH(+a)+HS(-a)=MnS+H2O HMnO2(-a)+HS(-a)+2H(+a)=MnS+2H2OT deltaH deltaS deltaG K Log(K) TC kJ J/K kJ C

5 -41.222 64.257 -59.095 1.26E+11 11.099 515 -38.992 72.138 -59.778 6.88E+10 10.837 1525 -37.07 78.695 -60.533 4.04E+10 10.606 2535 -35.309 84.506 -61.35 2.51E+10 10.4 3545 -33.616 89.912 -62.222 1.65E+10 10.217 4555 -31.949 95.072 -63.147 1.13E+10 10.053 5565 -30.296 100.034 -64.123 8.05E+09 9.906 6575 -28.623 104.911 -65.147 5.96E+09 9.775 7585 -26.911 109.758 -66.221 4.56E+09 9.659 8595 -25.146 114.619 -67.343 3.60E+09 9.556 95

100 -24.238 117.068 -67.922 3.23E+09 9.509 100

Formula FM Conc. Amount Amount Volume Formulag/mol wt-% mol g l or ml

MnOH(+a) 71.945 68.511 1 71.945 0 ml HMnO2(-a)HS(-a) 33.068 31.489 1 33.068 0 ml HS(-a)

g/mol wt-% mol g l or ml H(+a)MnS 86.998 82.845 1 86.998 21.75 mlH2O 18.015 17.155 1 18.015 19.646 ml MnS

H2O

HMnO2(-a)+HS(-a)+2H(+a)=MnS+2H2OdeltaH deltaS deltaG K Log(K)kJ J/K kJ

-149.378 164.306 -195.08 4.34E+36 36.638-145.77 177.055 -196.788 4.74E+35 35.676-142.57 187.974 -198.615 6.30E+34 34.799

-139.573 197.862 -200.544 9.94E+33 33.997-136.654 207.186 -202.57 1.83E+33 33.261-133.752 216.167 -204.687 3.84E+32 32.585-130.853 224.869 -206.892 9.16E+31 31.962-127.907 233.452 -209.184 2.44E+31 31.388

-124.89 241.998 -211.561 7.21E+30 30.858-121.777 250.569 -214.024 2.34E+30 30.369-120.177 254.885 -215.288 1.38E+30 30.139

FM Conc. Amount Amount Volumeg/mol wt-% mol g l or ml

87.945 71.483 1 87.945 0 ml33.068 26.878 1 33.068 0 ml

1.008 1.638 2 2.016 0 mlg/mol wt-% mol g l or ml

86.998 70.714 1 86.998 21.75 ml18.015 29.286 2 36.03 39.292 ml

Mn(+2a)+H2S(a)=MnS+2H(+a)T deltaH deltaS deltaG K Log(K)C kJ J/K kJ

5 48.709 35.394 38.864 5.02E-08 -7.29915 47.335 30.54 38.535 1.03E-07 -6.98625 46.103 26.337 38.251 1.99E-07 -6.70235 44.981 22.634 38.006 3.61E-07 -6.44345 43.953 19.35 37.797 6.22E-07 -6.20655 43.004 16.412 37.618 1.03E-06 -5.98965 42.115 13.744 37.468 1.63E-06 -5.78875 41.29 11.337 37.342 2.49E-06 -5.60385 40.525 9.173 37.24 3.70E-06 -5.43295 39.823 7.237 37.158 5.34E-06 -5.273

100 39.495 6.353 37.124 6.35E-06 -5.197

Formula FM Conc. Amount Amount Volumeg/mol wt-% mol g l or ml

Mn(+2a) 54.938 61.719 1 54.938 0H2S(a) 34.076 38.281 1 34.076 0

g/mol wt-% mol g l or mlFormula FM Conc. Amount Amount Volume

g/mol wt-% mol g l or mlMn(+2a) 54.938 61.719 1 54.938 0H2S(a) 34.076 38.281 1 34.076 0

g/mol wt-% mol g l or ml

Mn(+2a)+HS(-a)=MnS+H(+a)T deltaH deltaS deltaG K Log(K)C kJ J/K kJ

5 18.618 70.107 -0.882 1.47E+00 0.16615 20.771 77.717 -1.623 1.97E+00 0.29425 22.506 83.638 -2.431 2.67E+00 0.42635 24.026 88.654 -3.293 3.62E+00 0.55845 25.456 93.223 -4.203 4.90E+00 0.6955 26.856 97.554 -5.157 6.62E+00 0.82165 28.239 101.707 -6.153 8.92E+00 0.95175 29.654 105.832 -7.191 1.20E+01 1.07985 31.126 109.998 -8.27 1.61E+01 1.20695 32.674 114.261 -9.391 2.15E+01 1.333

100 33.484 116.445 -9.968 2.49E+01 1.395

Formula FM Conc. Amount Amount Volumeg/mol wt-% mol g l or ml

Mn(+2a) 54.938 62.425 1 54.938 0 mlHS(-a) 33.068 37.575 1 33.068 0 ml

g/mol wt-% mol g l or mlMnS 86.998 98.855 1 86.998 21.75 mlH(+a) 1.008 1.145 1 1.008 0 ml

MnOH(+a)+HS(-a)=MnS+H2O HMnO2(-a)+HS(-a)+2H(+a)=MnS+2H2OT deltaH deltaS deltaG K Log(K) TC kJ J/K kJ C

5 -41.222 64.257 -59.095 1.26E+11 11.099 515 -38.992 72.138 -59.778 6.88E+10 10.837 1525 -37.07 78.695 -60.533 4.04E+10 10.606 2535 -35.309 84.506 -61.35 2.51E+10 10.4 3545 -33.616 89.912 -62.222 1.65E+10 10.217 4555 -31.949 95.072 -63.147 1.13E+10 10.053 5565 -30.296 100.034 -64.123 8.05E+09 9.906 6575 -28.623 104.911 -65.147 5.96E+09 9.775 7585 -26.911 109.758 -66.221 4.56E+09 9.659 8595 -25.146 114.619 -67.343 3.60E+09 9.556 95

100 -24.238 117.068 -67.922 3.23E+09 9.509 100

Formula FM Conc. Amount Amount Volume Formulag/mol wt-% mol g l or ml

MnOH(+a) 71.945 68.511 1 71.945 0 ml HMnO2(-a)HS(-a) 33.068 31.489 1 33.068 0 ml HS(-a)

g/mol wt-% mol g l or ml H(+a)MnS 86.998 82.845 1 86.998 21.75 mlH2O 18.015 17.155 1 18.015 19.646 ml MnS

H2O

HMnO2(-a)+HS(-a)+2H(+a)=MnS+2H2OdeltaH deltaS deltaG K Log(K)kJ J/K kJ

-149.378 164.306 -195.08 4.34E+36 36.638-145.77 177.055 -196.788 4.74E+35 35.676-142.57 187.974 -198.615 6.30E+34 34.799

-139.573 197.862 -200.544 9.94E+33 33.997-136.654 207.186 -202.57 1.83E+33 33.261-133.752 216.167 -204.687 3.84E+32 32.585-130.853 224.869 -206.892 9.16E+31 31.962-127.907 233.452 -209.184 2.44E+31 31.388

-124.89 241.998 -211.561 7.21E+30 30.858-121.777 250.569 -214.024 2.34E+30 30.369-120.177 254.885 -215.288 1.38E+30 30.139

FM Conc. Amount Amount Volumeg/mol wt-% mol g l or ml

87.945 71.483 1 87.945 0 ml33.068 26.878 1 33.068 0 ml

1.008 1.638 2 2.016 0 mlg/mol wt-% mol g l or ml

86.998 70.714 1 86.998 21.75 ml18.015 29.286 2 36.03 39.292 ml